Cargando…

Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate

Two 3-nitro­phthalate dianions bridge two water-coordinated 2,2′-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacen...

Descripción completa

Detalles Bibliográficos
Autores principales: Han, Yin-Feng, Cheng, Chen, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009171/
https://www.ncbi.nlm.nih.gov/pubmed/21588899
http://dx.doi.org/10.1107/S1600536810043229
_version_ 1782194623793332224
author Han, Yin-Feng
Cheng, Chen
Ng, Seik Weng
author_facet Han, Yin-Feng
Cheng, Chen
Ng, Seik Weng
author_sort Han, Yin-Feng
collection PubMed
description Two 3-nitro­phthalate dianions bridge two water-coordinated 2,2′-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol­ecules are linked through the coordinated and solvent water mol­ecules to form a linear ribbon running along the a axis of the monoclinic unit cell.
format Text
id pubmed-3009171
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30091712010-12-30 Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate Han, Yin-Feng Cheng, Chen Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two 3-nitro­phthalate dianions bridge two water-coordinated 2,2′-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol­ecules are linked through the coordinated and solvent water mol­ecules to form a linear ribbon running along the a axis of the monoclinic unit cell. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009171/ /pubmed/21588899 http://dx.doi.org/10.1107/S1600536810043229 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Yin-Feng
Cheng, Chen
Ng, Seik Weng
Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title_full Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title_fullStr Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title_full_unstemmed Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title_short Bis(μ-3-nitro­phthalato-κ(2) O (1):O (2))bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)copper(II)] dihydrate
title_sort bis(μ-3-nitro­phthalato-κ(2) o (1):o (2))bis­[aqua­(2,2′-bipyridine-κ(2) n,n′)copper(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009171/
https://www.ncbi.nlm.nih.gov/pubmed/21588899
http://dx.doi.org/10.1107/S1600536810043229
work_keys_str_mv AT hanyinfeng bism3nitrophthalatok2o1o2bisaqua22bipyridinek2nncopperiidihydrate
AT chengchen bism3nitrophthalatok2o1o2bisaqua22bipyridinek2nncopperiidihydrate
AT ngseikweng bism3nitrophthalatok2o1o2bisaqua22bipyridinek2nncopperiidihydrate