3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid

The asymmetric unit of the title compound, C(21)H(18)O(3), contains two crystallographically independent mol­ecules. The two mol­ecules are linked into cyclic centrosymmetric dimers R (2) (2)(8) by O—H⋯O hydrogen bonds. The dihedral angles between the naphthalene ring system and the benzene ring are...

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Detalles Bibliográficos
Autores principales: Thenmozhi, S., ArulClement, J., MohanaKrishnan, A. K., SubbiahPandi, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009172/
https://www.ncbi.nlm.nih.gov/pubmed/21588991
http://dx.doi.org/10.1107/S1600536810040183
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author Thenmozhi, S.
ArulClement, J.
MohanaKrishnan, A. K.
SubbiahPandi, A.
author_facet Thenmozhi, S.
ArulClement, J.
MohanaKrishnan, A. K.
SubbiahPandi, A.
author_sort Thenmozhi, S.
collection PubMed
description The asymmetric unit of the title compound, C(21)H(18)O(3), contains two crystallographically independent mol­ecules. The two mol­ecules are linked into cyclic centrosymmetric dimers R (2) (2)(8) by O—H⋯O hydrogen bonds. The dihedral angles between the naphthalene ring system and the benzene ring are 87.0 (8) and 84.4 (2)° in the two mol­ecules. The crystal packing is stabilized by O—H⋯O, C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.664 (11) Å]. In one mol­ecule, the mesityl ring is disordered over two positions [occupancy ratio 0.690 (3):0.690 (3)].
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spelling pubmed-30091722010-12-30 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid Thenmozhi, S. ArulClement, J. MohanaKrishnan, A. K. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(21)H(18)O(3), contains two crystallographically independent mol­ecules. The two mol­ecules are linked into cyclic centrosymmetric dimers R (2) (2)(8) by O—H⋯O hydrogen bonds. The dihedral angles between the naphthalene ring system and the benzene ring are 87.0 (8) and 84.4 (2)° in the two mol­ecules. The crystal packing is stabilized by O—H⋯O, C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.664 (11) Å]. In one mol­ecule, the mesityl ring is disordered over two positions [occupancy ratio 0.690 (3):0.690 (3)]. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009172/ /pubmed/21588991 http://dx.doi.org/10.1107/S1600536810040183 Text en © Thenmozhi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thenmozhi, S.
ArulClement, J.
MohanaKrishnan, A. K.
SubbiahPandi, A.
3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title_full 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title_fullStr 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title_full_unstemmed 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title_short 3-(2,4,6-Trimethyl­benzo­yl)-2-naphthoic acid
title_sort 3-(2,4,6-trimethyl­benzo­yl)-2-naphthoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009172/
https://www.ncbi.nlm.nih.gov/pubmed/21588991
http://dx.doi.org/10.1107/S1600536810040183
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AT arulclementj 3246trimethylbenzoyl2naphthoicacid
AT mohanakrishnanak 3246trimethylbenzoyl2naphthoicacid
AT subbiahpandia 3246trimethylbenzoyl2naphthoicacid

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