Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]

In the title compound, {[NaTb(C(7)H(6)NO(2))(4)(H(2)O)(2)]·C(2)H(5)OH·H(2)O}(n), the Tb(III) atom is eight-coordinated in a slightly distorted square-anti­prismatic geometry defined by four carboxyl­ate O atoms and four pyridine N atoms. The bond lengths lie within the range 2.3000 (2)–2.326 (2) Å f...

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Detalles Bibliográficos
Autores principales: Lee, Taewoo, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009174/
https://www.ncbi.nlm.nih.gov/pubmed/21588794
http://dx.doi.org/10.1107/S1600536810038456
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author Lee, Taewoo
Kang, Sung Kwon
author_facet Lee, Taewoo
Kang, Sung Kwon
author_sort Lee, Taewoo
collection PubMed
description In the title compound, {[NaTb(C(7)H(6)NO(2))(4)(H(2)O)(2)]·C(2)H(5)OH·H(2)O}(n), the Tb(III) atom is eight-coordinated in a slightly distorted square-anti­prismatic geometry defined by four carboxyl­ate O atoms and four pyridine N atoms. The bond lengths lie within the range 2.3000 (2)–2.326 (2) Å for the Tb—O bonds and 2.543 (3)–2.553 (3) Å for the Tb—N bonds. The Na(I) atom is five-coordinated by two water O atoms and three carboxyl­ate O atoms in a distorted square-pyramidal geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-30091742010-12-30 Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate] Lee, Taewoo Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[NaTb(C(7)H(6)NO(2))(4)(H(2)O)(2)]·C(2)H(5)OH·H(2)O}(n), the Tb(III) atom is eight-coordinated in a slightly distorted square-anti­prismatic geometry defined by four carboxyl­ate O atoms and four pyridine N atoms. The bond lengths lie within the range 2.3000 (2)–2.326 (2) Å for the Tb—O bonds and 2.543 (3)–2.553 (3) Å for the Tb—N bonds. The Na(I) atom is five-coordinated by two water O atoms and three carboxyl­ate O atoms in a distorted square-pyramidal geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009174/ /pubmed/21588794 http://dx.doi.org/10.1107/S1600536810038456 Text en © Lee and Kang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Taewoo
Kang, Sung Kwon
Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title_full Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title_fullStr Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title_full_unstemmed Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title_short Poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(III)] ethanol monosolvate monohydrate]
title_sort poly[[diaqua­tris­(μ(2)-3-methyl­pyridine-2-carboxyl­ato)(3-methyl­pyridine-2-car­boxyl­ato)sodiumterbium(iii)] ethanol monosolvate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009174/
https://www.ncbi.nlm.nih.gov/pubmed/21588794
http://dx.doi.org/10.1107/S1600536810038456
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AT kangsungkwon polydiaquatrism23methylpyridine2carboxylato3methylpyridine2carboxylatosodiumterbiumiiiethanolmonosolvatemonohydrate

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