(4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine

The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis­ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the...

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Detalles Bibliográficos
Autores principales: Gzella, Andrzej K., Chrzanowska, Maria, Dreas, Agnieszka, Meissner, Zofia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009175/
https://www.ncbi.nlm.nih.gov/pubmed/21589035
http://dx.doi.org/10.1107/S1600536810040699
Descripción
Sumario:The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis­ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the mol­ecular packing is stabilized by non-classical C—H⋯O hydrogen bonds.

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