(4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine

The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis­ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the...

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Autores principales: Gzella, Andrzej K., Chrzanowska, Maria, Dreas, Agnieszka, Meissner, Zofia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009175/
https://www.ncbi.nlm.nih.gov/pubmed/21589035
http://dx.doi.org/10.1107/S1600536810040699
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author Gzella, Andrzej K.
Chrzanowska, Maria
Dreas, Agnieszka
Meissner, Zofia
author_facet Gzella, Andrzej K.
Chrzanowska, Maria
Dreas, Agnieszka
Meissner, Zofia
author_sort Gzella, Andrzej K.
collection PubMed
description The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis­ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the mol­ecular packing is stabilized by non-classical C—H⋯O hydrogen bonds.
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spelling pubmed-30091752010-12-30 (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine Gzella, Andrzej K. Chrzanowska, Maria Dreas, Agnieszka Meissner, Zofia Acta Crystallogr Sect E Struct Rep Online Organic Papers The absolute configuration of the title compound, C(20)H(23)NO(2), has been confirmed as 4S. The benzyl residue and H atom at the asymmetric C-atom centre occupy pseudo-axial and bis­ectional positions, respectively. The oxazolidine ring adopts an envelope conformation. In the crystal structure, the mol­ecular packing is stabilized by non-classical C—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009175/ /pubmed/21589035 http://dx.doi.org/10.1107/S1600536810040699 Text en © Gzella et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gzella, Andrzej K.
Chrzanowska, Maria
Dreas, Agnieszka
Meissner, Zofia
(4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title_full (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title_fullStr (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title_full_unstemmed (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title_short (4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
title_sort (4s)-(−)-4-benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009175/
https://www.ncbi.nlm.nih.gov/pubmed/21589035
http://dx.doi.org/10.1107/S1600536810040699
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AT chrzanowskamaria 4s4benzyl22dimethyl3otoluoyl13oxazolidine
AT dreasagnieszka 4s4benzyl22dimethyl3otoluoyl13oxazolidine
AT meissnerzofia 4s4benzyl22dimethyl3otoluoyl13oxazolidine

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