1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)

The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis­(1-adamant­yl)imidazolium (BAIM) cations and tetra­hedral tetra­chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adama...

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Detalles Bibliográficos
Autores principales: Ikhile, Monisola I., Bala, Muhammad D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009177/
https://www.ncbi.nlm.nih.gov/pubmed/21588906
http://dx.doi.org/10.1107/S1600536810043989
Descripción
Sumario:The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis­(1-adamant­yl)imidazolium (BAIM) cations and tetra­hedral tetra­chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adamantyl group located on a mirror plane. The Fe and two Cl atoms of the TCF anion are also located on the mirror plane. The cyclo­hexane rings of the adamantyl groups adopt normal chair conformations.

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