1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)

The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis­(1-adamant­yl)imidazolium (BAIM) cations and tetra­hedral tetra­chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adama...

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Detalles Bibliográficos
Autores principales: Ikhile, Monisola I., Bala, Muhammad D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009177/
https://www.ncbi.nlm.nih.gov/pubmed/21588906
http://dx.doi.org/10.1107/S1600536810043989
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author Ikhile, Monisola I.
Bala, Muhammad D.
author_facet Ikhile, Monisola I.
Bala, Muhammad D.
author_sort Ikhile, Monisola I.
collection PubMed
description The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis­(1-adamant­yl)imidazolium (BAIM) cations and tetra­hedral tetra­chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adamantyl group located on a mirror plane. The Fe and two Cl atoms of the TCF anion are also located on the mirror plane. The cyclo­hexane rings of the adamantyl groups adopt normal chair conformations.
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spelling pubmed-30091772010-12-30 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III) Ikhile, Monisola I. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(23)H(33)N(2))[FeCl(4)], consists of 1,3-bis­(1-adamant­yl)imidazolium (BAIM) cations and tetra­hedral tetra­chloridoferrate(III) (TCF) anions. The BAIM cation possesses m symmetry, with the central imidazole ring and four C atoms of each terminal adamantyl group located on a mirror plane. The Fe and two Cl atoms of the TCF anion are also located on the mirror plane. The cyclo­hexane rings of the adamantyl groups adopt normal chair conformations. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009177/ /pubmed/21588906 http://dx.doi.org/10.1107/S1600536810043989 Text en © Ikhile and Bala 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ikhile, Monisola I.
Bala, Muhammad D.
1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title_full 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title_fullStr 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title_full_unstemmed 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title_short 1,3-Bis(1-adamant­yl)imidazolium tetra­chloridoferrate(III)
title_sort 1,3-bis(1-adamant­yl)imidazolium tetra­chloridoferrate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009177/
https://www.ncbi.nlm.nih.gov/pubmed/21588906
http://dx.doi.org/10.1107/S1600536810043989
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AT balamuhammadd 13bis1adamantylimidazoliumtetrachloridoferrateiii

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