Tetra­kis[μ-2-(3,4-dimeth­oxy­phen­yl)acetato]-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis­{[2-(3,4-dimeth­oxy­phen­yl)acetato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)samarium(III)}

In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimeth­oxy­phen­yl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tric...

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Detalles Bibliográficos
Autores principales: Liu, Jia-Lu, Li, Hua-Qiong, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009179/
https://www.ncbi.nlm.nih.gov/pubmed/21588817
http://dx.doi.org/10.1107/S1600536810037153
Descripción
Sumario:In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimeth­oxy­phen­yl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes. An intra­molecular C—H⋯O hydrogen bond occurs. Inter­molecular C—H⋯O inter­actions are also present in the crystal.

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