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Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)samarium(III)}
In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tric...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009179/ https://www.ncbi.nlm.nih.gov/pubmed/21588817 http://dx.doi.org/10.1107/S1600536810037153 |
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| author | Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes. An intramolecular C—H⋯O hydrogen bond occurs. Intermolecular C—H⋯O interactions are also present in the crystal. |
| format | Text |
| id | pubmed-3009179 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30091792010-12-30 Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)samarium(III)} Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Sm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the Sm(III) ion is nine-coordinated by seven O atoms of five 2-(3,4-dimethoxyphenyl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes. An intramolecular C—H⋯O hydrogen bond occurs. Intermolecular C—H⋯O interactions are also present in the crystal. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009179/ /pubmed/21588817 http://dx.doi.org/10.1107/S1600536810037153 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Li, Hua-Qiong Zhao, Guo-Liang Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4) O:O′;κ(3) O,O′:O;κ(3) O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2) O,O′](1,10-phenanthroline-κ(2) N,N′)samarium(III)} |
| title | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)samarium(III)} |
| title_full | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)samarium(III)} |
| title_fullStr | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)samarium(III)} |
| title_full_unstemmed | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)samarium(III)} |
| title_short | Tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
O:O′;κ(3)
O,O′:O;κ(3)
O:O,O′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
O,O′](1,10-phenanthroline-κ(2)
N,N′)samarium(III)} |
| title_sort | tetrakis[μ-2-(3,4-dimethoxyphenyl)acetato]-κ(4)
o:o′;κ(3)
o,o′:o;κ(3)
o:o,o′-bis{[2-(3,4-dimethoxyphenyl)acetato-κ(2)
o,o′](1,10-phenanthroline-κ(2)
n,n′)samarium(iii)} |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009179/ https://www.ncbi.nlm.nih.gov/pubmed/21588817 http://dx.doi.org/10.1107/S1600536810037153 |
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