(μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)

In the title salt, [Zn(2)(C(2)H(8)N(2))(5)](ClO(4))(4), an ethyl­enediamine mol­ecule bridges two bis­(ethyl­enediamine)­zinc units; the five-coordinate Zn atoms show a trigonal–bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and...

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Detalles Bibliográficos
Autores principales: Ding, Man-Hua, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009181/
https://www.ncbi.nlm.nih.gov/pubmed/21588800
http://dx.doi.org/10.1107/S1600536810038730
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author Ding, Man-Hua
Ng, Seik Weng
author_facet Ding, Man-Hua
Ng, Seik Weng
author_sort Ding, Man-Hua
collection PubMed
description In the title salt, [Zn(2)(C(2)H(8)N(2))(5)](ClO(4))(4), an ethyl­enediamine mol­ecule bridges two bis­(ethyl­enediamine)­zinc units; the five-coordinate Zn atoms show a trigonal–bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation inter­acts weakly with the anion by N—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-30091812010-12-30 (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate) Ding, Man-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Zn(2)(C(2)H(8)N(2))(5)](ClO(4))(4), an ethyl­enediamine mol­ecule bridges two bis­(ethyl­enediamine)­zinc units; the five-coordinate Zn atoms show a trigonal–bipyramidal coordination geometry that is distorted towards square-pyramidal (that of one Zn atom is distorted by 12% and that of the other by 34%). The perchlorate ions are all disordered over two positions in a 1:1 ratio. The cation inter­acts weakly with the anion by N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009181/ /pubmed/21588800 http://dx.doi.org/10.1107/S1600536810038730 Text en © Ding and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Man-Hua
Ng, Seik Weng
(μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title_full (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title_fullStr (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title_full_unstemmed (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title_short (μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[bis­(ethane-1,2-diamine-κ(2) N,N′)zinc(II)] tetra­kis­(perchlorate)
title_sort (μ-ethane-1,2-diamine-κ(2) n:n′)bis­[bis­(ethane-1,2-diamine-κ(2) n,n′)zinc(ii)] tetra­kis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009181/
https://www.ncbi.nlm.nih.gov/pubmed/21588800
http://dx.doi.org/10.1107/S1600536810038730
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AT ngseikweng methane12diaminek2nnbisbisethane12diaminek2nnzinciitetrakisperchlorate

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