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α-Ba(2)P(2)O(7)

Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The ortho­rhom­bic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry),...

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Autores principales: Zakaria, Driss, Erragh, Fatima, Oudahmane, Abdelghani, El-Ghozzi, Malika, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009187/
https://www.ncbi.nlm.nih.gov/pubmed/21588791
http://dx.doi.org/10.1107/S1600536810043539
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author Zakaria, Driss
Erragh, Fatima
Oudahmane, Abdelghani
El-Ghozzi, Malika
Avignant, Daniel
author_facet Zakaria, Driss
Erragh, Fatima
Oudahmane, Abdelghani
El-Ghozzi, Malika
Avignant, Daniel
author_sort Zakaria, Driss
collection PubMed
description Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The ortho­rhom­bic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry), with Ba—O distances in the ranges 2.7585 (10)–3.0850 (6) and 2.5794 (13)–2.9313 (4) Å. These polyhedra are further linked by sharing corners along [010] and either edges or triangular faces perpendicularly to [010] to form the three-dimensional framework. This polyhedral linkage delimits large channels parallel to [010] where the P(2)O(7) diphosphate anions are located. These groups (symmetry m) are characterized by a P—O—P angle of 131.52 (9)° and an eclipsed conformation. They are connected to the BaO(9) polyhedra through edges and corners.
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spelling pubmed-30091872010-12-30 α-Ba(2)P(2)O(7) Zakaria, Driss Erragh, Fatima Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The ortho­rhom­bic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry), with Ba—O distances in the ranges 2.7585 (10)–3.0850 (6) and 2.5794 (13)–2.9313 (4) Å. These polyhedra are further linked by sharing corners along [010] and either edges or triangular faces perpendicularly to [010] to form the three-dimensional framework. This polyhedral linkage delimits large channels parallel to [010] where the P(2)O(7) diphosphate anions are located. These groups (symmetry m) are characterized by a P—O—P angle of 131.52 (9)° and an eclipsed conformation. They are connected to the BaO(9) polyhedra through edges and corners. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009187/ /pubmed/21588791 http://dx.doi.org/10.1107/S1600536810043539 Text en © Zakaria et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zakaria, Driss
Erragh, Fatima
Oudahmane, Abdelghani
El-Ghozzi, Malika
Avignant, Daniel
α-Ba(2)P(2)O(7)
title α-Ba(2)P(2)O(7)
title_full α-Ba(2)P(2)O(7)
title_fullStr α-Ba(2)P(2)O(7)
title_full_unstemmed α-Ba(2)P(2)O(7)
title_short α-Ba(2)P(2)O(7)
title_sort α-ba(2)p(2)o(7)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009187/
https://www.ncbi.nlm.nih.gov/pubmed/21588791
http://dx.doi.org/10.1107/S1600536810043539
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