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α-Ba(2)P(2)O(7)
Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The orthorhombic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry),...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009187/ https://www.ncbi.nlm.nih.gov/pubmed/21588791 http://dx.doi.org/10.1107/S1600536810043539 |
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author | Zakaria, Driss Erragh, Fatima Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel |
author_facet | Zakaria, Driss Erragh, Fatima Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel |
author_sort | Zakaria, Driss |
collection | PubMed |
description | Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The orthorhombic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry), with Ba—O distances in the ranges 2.7585 (10)–3.0850 (6) and 2.5794 (13)–2.9313 (4) Å. These polyhedra are further linked by sharing corners along [010] and either edges or triangular faces perpendicularly to [010] to form the three-dimensional framework. This polyhedral linkage delimits large channels parallel to [010] where the P(2)O(7) diphosphate anions are located. These groups (symmetry m) are characterized by a P—O—P angle of 131.52 (9)° and an eclipsed conformation. They are connected to the BaO(9) polyhedra through edges and corners. |
format | Text |
id | pubmed-3009187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30091872010-12-30 α-Ba(2)P(2)O(7) Zakaria, Driss Erragh, Fatima Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The orthorhombic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry), with Ba—O distances in the ranges 2.7585 (10)–3.0850 (6) and 2.5794 (13)–2.9313 (4) Å. These polyhedra are further linked by sharing corners along [010] and either edges or triangular faces perpendicularly to [010] to form the three-dimensional framework. This polyhedral linkage delimits large channels parallel to [010] where the P(2)O(7) diphosphate anions are located. These groups (symmetry m) are characterized by a P—O—P angle of 131.52 (9)° and an eclipsed conformation. They are connected to the BaO(9) polyhedra through edges and corners. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009187/ /pubmed/21588791 http://dx.doi.org/10.1107/S1600536810043539 Text en © Zakaria et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Zakaria, Driss Erragh, Fatima Oudahmane, Abdelghani El-Ghozzi, Malika Avignant, Daniel α-Ba(2)P(2)O(7) |
title | α-Ba(2)P(2)O(7)
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title_full | α-Ba(2)P(2)O(7)
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title_fullStr | α-Ba(2)P(2)O(7)
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title_full_unstemmed | α-Ba(2)P(2)O(7)
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title_short | α-Ba(2)P(2)O(7)
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title_sort | α-ba(2)p(2)o(7) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009187/ https://www.ncbi.nlm.nih.gov/pubmed/21588791 http://dx.doi.org/10.1107/S1600536810043539 |
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