Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate

In the title compound, [Co(C(10)H(12)NO(2))(3)]·H(2)O, the Co(III) ion is coordinated by three O atoms and three N atoms from three bidentate 2-eth­oxy-6-(methyl­imino­meth­yl)phenolate ligands in a slightly distorted octa­hedral environment. The water mol­ecule connects two ligands by O—H⋯O hydroge...

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Detalles Bibliográficos
Autores principales: Huang, Yin Dan, Zhang, Shu-Hua, Qin, Jiang Ke, Chen, Fu Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009188/
https://www.ncbi.nlm.nih.gov/pubmed/21588832
http://dx.doi.org/10.1107/S1600536810040043
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author Huang, Yin Dan
Zhang, Shu-Hua
Qin, Jiang Ke
Chen, Fu Li
author_facet Huang, Yin Dan
Zhang, Shu-Hua
Qin, Jiang Ke
Chen, Fu Li
author_sort Huang, Yin Dan
collection PubMed
description In the title compound, [Co(C(10)H(12)NO(2))(3)]·H(2)O, the Co(III) ion is coordinated by three O atoms and three N atoms from three bidentate 2-eth­oxy-6-(methyl­imino­meth­yl)phenolate ligands in a slightly distorted octa­hedral environment. The water mol­ecule connects two ligands by O—H⋯O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412 (15) and 0.588 (15).
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spelling pubmed-30091882010-12-30 Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate Huang, Yin Dan Zhang, Shu-Hua Qin, Jiang Ke Chen, Fu Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(12)NO(2))(3)]·H(2)O, the Co(III) ion is coordinated by three O atoms and three N atoms from three bidentate 2-eth­oxy-6-(methyl­imino­meth­yl)phenolate ligands in a slightly distorted octa­hedral environment. The water mol­ecule connects two ligands by O—H⋯O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412 (15) and 0.588 (15). International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009188/ /pubmed/21588832 http://dx.doi.org/10.1107/S1600536810040043 Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Yin Dan
Zhang, Shu-Hua
Qin, Jiang Ke
Chen, Fu Li
Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title_full Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title_fullStr Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title_full_unstemmed Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title_short Tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) N,O (1)]cobalt(III) monohydrate
title_sort tris[2-eth­oxy-6-(methyl­imino­meth­yl)phenolato-κ(2) n,o (1)]cobalt(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009188/
https://www.ncbi.nlm.nih.gov/pubmed/21588832
http://dx.doi.org/10.1107/S1600536810040043
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