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trans-Bromido(pyrimidinyl-κC (2))bis(triphenylphosphane-κP)palladium(II)
In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P—Pd—P = 176.743 (17)°], while the pyrimidinyl li...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009198/ https://www.ncbi.nlm.nih.gov/pubmed/21588792 http://dx.doi.org/10.1107/S1600536810038511 |
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| author | Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway |
| author_facet | Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway |
| author_sort | Lee, Gene-Hsiang |
| collection | PubMed |
| description | In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P—Pd—P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C—Pd—Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound. |
| format | Text |
| id | pubmed-3009198 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30091982010-12-30 trans-Bromido(pyrimidinyl-κC (2))bis(triphenylphosphane-κP)palladium(II) Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P—Pd—P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C—Pd—Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009198/ /pubmed/21588792 http://dx.doi.org/10.1107/S1600536810038511 Text en © Lee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, Gene-Hsiang Wang, Hsiao-Fen Yih, Kuang-Hway trans-Bromido(pyrimidinyl-κC (2))bis(triphenylphosphane-κP)palladium(II) |
| title |
trans-Bromido(pyrimidinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
| title_full |
trans-Bromido(pyrimidinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
| title_fullStr |
trans-Bromido(pyrimidinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
| title_full_unstemmed |
trans-Bromido(pyrimidinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
| title_short |
trans-Bromido(pyrimidinyl-κC
(2))bis(triphenylphosphane-κP)palladium(II) |
| title_sort | trans-bromido(pyrimidinyl-κc
(2))bis(triphenylphosphane-κp)palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009198/ https://www.ncbi.nlm.nih.gov/pubmed/21588792 http://dx.doi.org/10.1107/S1600536810038511 |
| work_keys_str_mv | AT leegenehsiang transbromidopyrimidinylkc2bistriphenylphosphanekppalladiumii AT wanghsiaofen transbromidopyrimidinylkc2bistriphenylphosphanekppalladiumii AT yihkuanghway transbromidopyrimidinylkc2bistriphenylphosphanekppalladiumii |