catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]

The asymmetric unit of the polymeric title compound, {[Zn(C(8)H(12)N(6))(H(2)O)(4)](C(14)H(8)O(4))}(n) or {[Zn(BTB)(H(2)O)(4)](BPDC)}(n) [BTB is 1,4-bis­(1,2,4-triazol-1-yl)butane and H(2)BPDC is biphenyl-4,4′-dicarb­oxy­lic acid], contains half a [Zn(BTB)(H(2)O)(4)](2+) cation and half a BPDC anion...

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Detalles Bibliográficos
Autor principal: Jiao, Chang-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009203/
https://www.ncbi.nlm.nih.gov/pubmed/21588836
http://dx.doi.org/10.1107/S160053681003970X
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author Jiao, Chang-Mei
author_facet Jiao, Chang-Mei
author_sort Jiao, Chang-Mei
collection PubMed
description The asymmetric unit of the polymeric title compound, {[Zn(C(8)H(12)N(6))(H(2)O)(4)](C(14)H(8)O(4))}(n) or {[Zn(BTB)(H(2)O)(4)](BPDC)}(n) [BTB is 1,4-bis­(1,2,4-triazol-1-yl)butane and H(2)BPDC is biphenyl-4,4′-dicarb­oxy­lic acid], contains half a [Zn(BTB)(H(2)O)(4)](2+) cation and half a BPDC anion, both ions lying about a crystallographic inversion centre. The crystal structure consists of zigzag polymeric cationic chains parallel to the c axis and uncoordinated anions linked into a three-dimensional supra­molecular architecture by O—H⋯O, C—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-30092032010-12-30 catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate] Jiao, Chang-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title compound, {[Zn(C(8)H(12)N(6))(H(2)O)(4)](C(14)H(8)O(4))}(n) or {[Zn(BTB)(H(2)O)(4)](BPDC)}(n) [BTB is 1,4-bis­(1,2,4-triazol-1-yl)butane and H(2)BPDC is biphenyl-4,4′-dicarb­oxy­lic acid], contains half a [Zn(BTB)(H(2)O)(4)](2+) cation and half a BPDC anion, both ions lying about a crystallographic inversion centre. The crystal structure consists of zigzag polymeric cationic chains parallel to the c axis and uncoordinated anions linked into a three-dimensional supra­molecular architecture by O—H⋯O, C—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009203/ /pubmed/21588836 http://dx.doi.org/10.1107/S160053681003970X Text en © Chang-Mei Jiao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiao, Chang-Mei
catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title_full catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title_fullStr catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title_full_unstemmed catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title_short catena-Poly[[[tetra­aqua­zinc(II)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) N (4):N (4′)] biphenyl-4,4′-dicarboxyl­ate]
title_sort catena-poly[[[tetra­aqua­zinc(ii)]-μ-1,4-bis­(1,2,4-triazol-1-yl)butane-κ(2) n (4):n (4′)] biphenyl-4,4′-dicarboxyl­ate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009203/
https://www.ncbi.nlm.nih.gov/pubmed/21588836
http://dx.doi.org/10.1107/S160053681003970X
work_keys_str_mv AT jiaochangmei catenapolytetraaquazinciim14bis124triazol1ylbutanek2n4n4biphenyl44dicarboxylate

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