Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]

In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine ligands and one O atom from a trifluoro­methane­sulfonate anion in a distorted T-type coordination geome...

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Detalles Bibliográficos
Autores principales: Wang, Huan-Huan, Zhang, Chao-Yan, Cui, Yue, Gao, Qian, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009204/
https://www.ncbi.nlm.nih.gov/pubmed/21588909
http://dx.doi.org/10.1107/S1600536810043631
Descripción
Sumario:In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine ligands and one O atom from a trifluoro­methane­sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π–π inter­actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.

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