Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]

In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine ligands and one O atom from a trifluoro­methane­sulfonate anion in a distorted T-type coordination geome...

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Detalles Bibliográficos
Autores principales: Wang, Huan-Huan, Zhang, Chao-Yan, Cui, Yue, Gao, Qian, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009204/
https://www.ncbi.nlm.nih.gov/pubmed/21588909
http://dx.doi.org/10.1107/S1600536810043631
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author Wang, Huan-Huan
Zhang, Chao-Yan
Cui, Yue
Gao, Qian
Xie, Ya-Bo
author_facet Wang, Huan-Huan
Zhang, Chao-Yan
Cui, Yue
Gao, Qian
Xie, Ya-Bo
author_sort Wang, Huan-Huan
collection PubMed
description In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine ligands and one O atom from a trifluoro­methane­sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π–π inter­actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.
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spelling pubmed-30092042010-12-30 Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)] Wang, Huan-Huan Zhang, Chao-Yan Cui, Yue Gao, Qian Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine ligands and one O atom from a trifluoro­methane­sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π–π inter­actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009204/ /pubmed/21588909 http://dx.doi.org/10.1107/S1600536810043631 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Huan-Huan
Zhang, Chao-Yan
Cui, Yue
Gao, Qian
Xie, Ya-Bo
Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title_full Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title_fullStr Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title_full_unstemmed Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title_short Bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κN (1)]bis­[(trifluoro­methanesulfonato-κO)silver(I)]
title_sort bis[μ-4-methyl-2-(2-pyridyl­methyl­sulfan­yl)pyrimidine-κn (1)]bis­[(trifluoro­methanesulfonato-κo)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009204/
https://www.ncbi.nlm.nih.gov/pubmed/21588909
http://dx.doi.org/10.1107/S1600536810043631
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