catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]

In the title complex, [Ca(C(10)H(6)NO(2))(2)(H(2)O)(2)](n), the Ca(II) ion is eight-coordinated by six carboxyl­ate O atoms from four separate quinoline-3-carboxyl­ate ligands, two of which are bidentate chelate and two bridging, and two water mol­ecules in a distorted square-anti­prismatic geometry...

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Detalles Bibliográficos
Autores principales: Miao, Dong-Liang, Li, Shi-Jie, Song, Wen-Dong, Liu, Juan-Hua, Li, Xiao-Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009206/
https://www.ncbi.nlm.nih.gov/pubmed/21588864
http://dx.doi.org/10.1107/S1600536810039401
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author Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Liu, Juan-Hua
Li, Xiao-Fei
author_facet Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Liu, Juan-Hua
Li, Xiao-Fei
author_sort Miao, Dong-Liang
collection PubMed
description In the title complex, [Ca(C(10)H(6)NO(2))(2)(H(2)O)(2)](n), the Ca(II) ion is eight-coordinated by six carboxyl­ate O atoms from four separate quinoline-3-carboxyl­ate ligands, two of which are bidentate chelate and two bridging, and two water mol­ecules in a distorted square-anti­prismatic geometry. The bridging groups form a polymeric chain substructure extending along the c axis, the chains being connected by coordinated-water O—H⋯N and O—H⋯O(carboxyl­ate) hydrogen bonds into a three-dimensional framework structure.
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spelling pubmed-30092062010-12-30 catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)] Miao, Dong-Liang Li, Shi-Jie Song, Wen-Dong Liu, Juan-Hua Li, Xiao-Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ca(C(10)H(6)NO(2))(2)(H(2)O)(2)](n), the Ca(II) ion is eight-coordinated by six carboxyl­ate O atoms from four separate quinoline-3-carboxyl­ate ligands, two of which are bidentate chelate and two bridging, and two water mol­ecules in a distorted square-anti­prismatic geometry. The bridging groups form a polymeric chain substructure extending along the c axis, the chains being connected by coordinated-water O—H⋯N and O—H⋯O(carboxyl­ate) hydrogen bonds into a three-dimensional framework structure. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009206/ /pubmed/21588864 http://dx.doi.org/10.1107/S1600536810039401 Text en © Miao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Dong-Liang
Li, Shi-Jie
Song, Wen-Dong
Liu, Juan-Hua
Li, Xiao-Fei
catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title_full catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title_fullStr catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title_full_unstemmed catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title_short catena-Poly[[diaqua­calcium(II)]-bis­(μ-quinoline-3-carboxyl­ato)]
title_sort catena-poly[[diaqua­calcium(ii)]-bis­(μ-quinoline-3-carboxyl­ato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009206/
https://www.ncbi.nlm.nih.gov/pubmed/21588864
http://dx.doi.org/10.1107/S1600536810039401
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