4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate

The title compound, C(9)H(14)N(2)O, exists in the zwitterionic form in the crystal. The cyclo­octane ring adopts a twisted boat-chair conformation. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into sheets lying parallel to bc. The structure is also stabilized by π–π inter...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Ragavan, R. Venkat, Vijayakumar, V., Sarveswari, S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009207/
https://www.ncbi.nlm.nih.gov/pubmed/21589177
http://dx.doi.org/10.1107/S1600536810043904
_version_ 1782194632434647040
author Fun, Hoong-Kun
Yeap, Chin Sing
Ragavan, R. Venkat
Vijayakumar, V.
Sarveswari, S.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Ragavan, R. Venkat
Vijayakumar, V.
Sarveswari, S.
author_sort Fun, Hoong-Kun
collection PubMed
description The title compound, C(9)H(14)N(2)O, exists in the zwitterionic form in the crystal. The cyclo­octane ring adopts a twisted boat-chair conformation. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into sheets lying parallel to bc. The structure is also stabilized by π–π inter­actions, with a centroid-to-centroid distance of 3.5684 (8) Å.
format Text
id pubmed-3009207
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092072010-12-30 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate Fun, Hoong-Kun Yeap, Chin Sing Ragavan, R. Venkat Vijayakumar, V. Sarveswari, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(14)N(2)O, exists in the zwitterionic form in the crystal. The cyclo­octane ring adopts a twisted boat-chair conformation. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into sheets lying parallel to bc. The structure is also stabilized by π–π inter­actions, with a centroid-to-centroid distance of 3.5684 (8) Å. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009207/ /pubmed/21589177 http://dx.doi.org/10.1107/S1600536810043904 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Ragavan, R. Venkat
Vijayakumar, V.
Sarveswari, S.
4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title_full 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title_fullStr 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title_full_unstemmed 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title_short 4,5,6,7,8,9-Hexahydro-2H-cyclo­octa[c]pyrazol-1-ium-3-olate
title_sort 4,5,6,7,8,9-hexahydro-2h-cyclo­octa[c]pyrazol-1-ium-3-olate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009207/
https://www.ncbi.nlm.nih.gov/pubmed/21589177
http://dx.doi.org/10.1107/S1600536810043904
work_keys_str_mv AT funhoongkun 456789hexahydro2hcyclooctacpyrazol1ium3olate
AT yeapchinsing 456789hexahydro2hcyclooctacpyrazol1ium3olate
AT ragavanrvenkat 456789hexahydro2hcyclooctacpyrazol1ium3olate
AT vijayakumarv 456789hexahydro2hcyclooctacpyrazol1ium3olate
AT sarveswaris 456789hexahydro2hcyclooctacpyrazol1ium3olate

Ejemplares similares