Cargando…
Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate
In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The uncoordinated O atom o...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009208/ https://www.ncbi.nlm.nih.gov/pubmed/21588844 http://dx.doi.org/10.1107/S1600536810040602 |
Sumario: | In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intramolecular hydrogen bond to the coordinated water molecule. The crystal packing is stabilized by intermolecular O—H⋯O hydrogen bonds involving the Hc anions, the coordinated water molecule, the nitrate anion and the uncoordinated water molecule. |
---|