Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate

In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa­hedral geometry. The uncoordinated O atom o...

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Detalles Bibliográficos
Autores principales: Guo, Gui-Quan, Deng, Ji-Hua, Chen, Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009208/
https://www.ncbi.nlm.nih.gov/pubmed/21588844
http://dx.doi.org/10.1107/S1600536810040602
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author Guo, Gui-Quan
Deng, Ji-Hua
Chen, Jing
author_facet Guo, Gui-Quan
Deng, Ji-Hua
Chen, Jing
author_sort Guo, Gui-Quan
collection PubMed
description In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa­hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra­molecular hydrogen bond to the coordinated water mol­ecule. The crystal packing is stabilized by inter­molecular O—H⋯O hydrogen bonds involving the Hc anions, the coordinated water mol­ecule, the nitrate anion and the uncoordinated water mol­ecule.
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spelling pubmed-30092082010-12-30 Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate Guo, Gui-Quan Deng, Ji-Hua Chen, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa­hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra­molecular hydrogen bond to the coordinated water mol­ecule. The crystal packing is stabilized by inter­molecular O—H⋯O hydrogen bonds involving the Hc anions, the coordinated water mol­ecule, the nitrate anion and the uncoordinated water mol­ecule. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009208/ /pubmed/21588844 http://dx.doi.org/10.1107/S1600536810040602 Text en © Guo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Gui-Quan
Deng, Ji-Hua
Chen, Jing
Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title_full Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title_fullStr Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title_full_unstemmed Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title_short Aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(II) nitrate monohydrate
title_sort aqua­(hippurato)bis­(1,10-phenanthroline)cobalt(ii) nitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009208/
https://www.ncbi.nlm.nih.gov/pubmed/21588844
http://dx.doi.org/10.1107/S1600536810040602
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