Cargando…

2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene

In the title mol­ecule {systematic name: [2,7-dimethoxy-8-(4-phenoxybenzoyl)naphthalen-1-yl](4-phenoxyphenyl)methan­one}, C(38)H(28)O(6), the 4-phen­oxy­benzoyl units adopt a syn orientation with respect to the naphthalene ring system. The inter­nal benzene rings, A and B, make dihedral angles of 86...

Descripción completa

Detalles Bibliográficos
Autores principales: Hijikata, Daichi, Takada, Teruhisa, Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009209/
https://www.ncbi.nlm.nih.gov/pubmed/21589079
http://dx.doi.org/10.1107/S1600536810042170
_version_ 1782194632899166208
author Hijikata, Daichi
Takada, Teruhisa
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Hijikata, Daichi
Takada, Teruhisa
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Hijikata, Daichi
collection PubMed
description In the title mol­ecule {systematic name: [2,7-dimethoxy-8-(4-phenoxybenzoyl)naphthalen-1-yl](4-phenoxyphenyl)methan­one}, C(38)H(28)O(6), the 4-phen­oxy­benzoyl units adopt a syn orientation with respect to the naphthalene ring system. The inter­nal benzene rings, A and B, make dihedral angles of 86.72 (5) and 79.22 (5)° with the naphthalene ring system. The two terminal benzene rings, C and D, of the 4-phen­oxy­benzoyl groups are twisted with respect to benzene rings A and B, with dihedral angles of A/C = 62.72 (8) and B/D = 87.61 (6)°. In the crystal, H atoms in the naphthalene system make two types of inter­molecular C—H⋯O inter­actions with the carbonyl O atom and the phenyl etheral O atom of neighbouring mol­ecules. Mol­ecules are further linked by C—H⋯π inter­actions involving a H atom of terminal benzene ring D and the π-system of the inter­nal benzene ring A, forming dimers centered about an inversion center.
format Text
id pubmed-3009209
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092092010-12-30 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene Hijikata, Daichi Takada, Teruhisa Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule {systematic name: [2,7-dimethoxy-8-(4-phenoxybenzoyl)naphthalen-1-yl](4-phenoxyphenyl)methan­one}, C(38)H(28)O(6), the 4-phen­oxy­benzoyl units adopt a syn orientation with respect to the naphthalene ring system. The inter­nal benzene rings, A and B, make dihedral angles of 86.72 (5) and 79.22 (5)° with the naphthalene ring system. The two terminal benzene rings, C and D, of the 4-phen­oxy­benzoyl groups are twisted with respect to benzene rings A and B, with dihedral angles of A/C = 62.72 (8) and B/D = 87.61 (6)°. In the crystal, H atoms in the naphthalene system make two types of inter­molecular C—H⋯O inter­actions with the carbonyl O atom and the phenyl etheral O atom of neighbouring mol­ecules. Mol­ecules are further linked by C—H⋯π inter­actions involving a H atom of terminal benzene ring D and the π-system of the inter­nal benzene ring A, forming dimers centered about an inversion center. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009209/ /pubmed/21589079 http://dx.doi.org/10.1107/S1600536810042170 Text en © Hijikata et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hijikata, Daichi
Takada, Teruhisa
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title_full 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title_fullStr 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title_full_unstemmed 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title_short 2,7-Dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
title_sort 2,7-dimeth­oxy-1,8-bis­(4-phen­oxy­benzo­yl)naphthalene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009209/
https://www.ncbi.nlm.nih.gov/pubmed/21589079
http://dx.doi.org/10.1107/S1600536810042170
work_keys_str_mv AT hijikatadaichi 27dimethoxy18bis4phenoxybenzoylnaphthalene
AT takadateruhisa 27dimethoxy18bis4phenoxybenzoylnaphthalene
AT nagasawaatsushi 27dimethoxy18bis4phenoxybenzoylnaphthalene
AT okamotoakiko 27dimethoxy18bis4phenoxybenzoylnaphthalene
AT yonezawanoriyuki 27dimethoxy18bis4phenoxybenzoylnaphthalene