Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate

In the title compound, [Cu(CH(3)CN)(C(13)H(10)N(2))(2)](BF(4))(2), the fivefold-coordinate Cu(II) atom is located on a twofold rotation axis, imposing twofold symmetry to the complete cation. The structure exhibits disorder of the anion, which was successfully refined using a two-site model with 0.8...

Descripción completa

Detalles Bibliográficos
Autor principal: Watton, Stephen P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009216/
https://www.ncbi.nlm.nih.gov/pubmed/21588802
http://dx.doi.org/10.1107/S1600536810038845
_version_ 1782194634583179264
author Watton, Stephen P.
author_facet Watton, Stephen P.
author_sort Watton, Stephen P.
collection PubMed
description In the title compound, [Cu(CH(3)CN)(C(13)H(10)N(2))(2)](BF(4))(2), the fivefold-coordinate Cu(II) atom is located on a twofold rotation axis, imposing twofold symmetry to the complete cation. The structure exhibits disorder of the anion, which was successfully refined using a two-site model with 0.810 (3):0.190 (3) occupancy. The methyl group of the acetonitrile ligand is likewise disordered, here about the twofold rotation axis in a 1:1 ratio.
format Text
id pubmed-3009216
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092162010-12-30 Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate Watton, Stephen P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(CH(3)CN)(C(13)H(10)N(2))(2)](BF(4))(2), the fivefold-coordinate Cu(II) atom is located on a twofold rotation axis, imposing twofold symmetry to the complete cation. The structure exhibits disorder of the anion, which was successfully refined using a two-site model with 0.810 (3):0.190 (3) occupancy. The methyl group of the acetonitrile ligand is likewise disordered, here about the twofold rotation axis in a 1:1 ratio. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009216/ /pubmed/21588802 http://dx.doi.org/10.1107/S1600536810038845 Text en © Stephen P. Watton 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Watton, Stephen P.
Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title_full Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title_fullStr Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title_full_unstemmed Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title_short Acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(II) tetra­fluoridoborate
title_sort acetonitrile­bis­(2-methyl-1,10-phenanthroline)copper(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009216/
https://www.ncbi.nlm.nih.gov/pubmed/21588802
http://dx.doi.org/10.1107/S1600536810038845
work_keys_str_mv AT wattonstephenp acetonitrilebis2methyl110phenanthrolinecopperiitetrafluoridoborate

Ejemplares similares