trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate

The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter­molecular contacts b...

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Detalles Bibliográficos
Autores principales: Burgoyne, Andrew R., Meijboom, Reinout, Muller, Alfred, Omondi, Bernard O.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009219/
https://www.ncbi.nlm.nih.gov/pubmed/21588819
http://dx.doi.org/10.1107/S1600536810039814
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author Burgoyne, Andrew R.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard O.
author_facet Burgoyne, Andrew R.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard O.
author_sort Burgoyne, Andrew R.
collection PubMed
description The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter­molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter­actions between the acetone solvent mol­ecule and the Cl—Rh unit results in a reduced P—Rh—Cl angle of 86.675 (15)°.
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spelling pubmed-30092192010-12-30 trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate Burgoyne, Andrew R. Meijboom, Reinout Muller, Alfred Omondi, Bernard O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P—Rh—P angle of 175.27 (2)° and Rh—P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter­molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter­actions between the acetone solvent mol­ecule and the Cl—Rh unit results in a reduced P—Rh—Cl angle of 86.675 (15)°. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009219/ /pubmed/21588819 http://dx.doi.org/10.1107/S1600536810039814 Text en © Burgoyne et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Burgoyne, Andrew R.
Meijboom, Reinout
Muller, Alfred
Omondi, Bernard O.
trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_full trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_fullStr trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_full_unstemmed trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_short trans-Carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(I) acetone monosolvate
title_sort trans-carbonyl­chloridobis[tris­(4-chloro­phen­yl)phosphane]rhodium(i) acetone monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009219/
https://www.ncbi.nlm.nih.gov/pubmed/21588819
http://dx.doi.org/10.1107/S1600536810039814
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AT meijboomreinout transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate
AT mulleralfred transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate
AT omondibernardo transcarbonylchloridobistris4chlorophenylphosphanerhodiumiacetonemonosolvate

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