(E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione

The title compound, C(15)H(14)O(4), was prepared by the reaction of 2,2-dimethyl-1,3-dioxane-4,6-dione and (Z)-3-phenyl­acryl­aldehyde in ethanol. The dioxane ring is in a sofa conformation with the C atom bonded to the two methyl groups forming the flap. With the exception of the flap atom and the...

Descripción completa

Detalles Bibliográficos
Autor principal: Zeng, Wu-Lan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009221/
https://www.ncbi.nlm.nih.gov/pubmed/21589113
http://dx.doi.org/10.1107/S1600536810042534
_version_ 1782194635775410176
author Zeng, Wu-Lan
author_facet Zeng, Wu-Lan
author_sort Zeng, Wu-Lan
collection PubMed
description The title compound, C(15)H(14)O(4), was prepared by the reaction of 2,2-dimethyl-1,3-dioxane-4,6-dione and (Z)-3-phenyl­acryl­aldehyde in ethanol. The dioxane ring is in a sofa conformation with the C atom bonded to the two methyl groups forming the flap. With the exception of the flap atom and the methyl group C atoms, all other non-H atoms are essentially planar, with an r.m.s. deviation of 0.067 (1) Å. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.
format Text
id pubmed-3009221
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092212010-12-30 (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione Zeng, Wu-Lan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(14)O(4), was prepared by the reaction of 2,2-dimethyl-1,3-dioxane-4,6-dione and (Z)-3-phenyl­acryl­aldehyde in ethanol. The dioxane ring is in a sofa conformation with the C atom bonded to the two methyl groups forming the flap. With the exception of the flap atom and the methyl group C atoms, all other non-H atoms are essentially planar, with an r.m.s. deviation of 0.067 (1) Å. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009221/ /pubmed/21589113 http://dx.doi.org/10.1107/S1600536810042534 Text en © Wu-Lan Zeng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zeng, Wu-Lan
(E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title_full (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title_fullStr (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title_full_unstemmed (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title_short (E)-2,2-Dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
title_sort (e)-2,2-dimethyl-5-(3-phenyl­allyl­idene)-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009221/
https://www.ncbi.nlm.nih.gov/pubmed/21589113
http://dx.doi.org/10.1107/S1600536810042534
work_keys_str_mv AT zengwulan e22dimethyl53phenylallylidene13dioxane46dione

Ejemplares similares