1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane

The –SCH(2)CH(2)CH(2)CH(2)S– portion of the title compound, C(12)H(14)N(2)S(2), adopts an extended zigzag conformation. The angles at the tetra­hedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S—C—C and C—C—C respectively] from the idealized tetra­hedral angle. The mol...

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Detalles Bibliográficos
Autores principales: Akbar, Muhammad, Quereshi, Fahim Ashraf, Nasir, Waqar, Adnan, Ahmad, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009222/
https://www.ncbi.nlm.nih.gov/pubmed/21589034
http://dx.doi.org/10.1107/S1600536810041103
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author Akbar, Muhammad
Quereshi, Fahim Ashraf
Nasir, Waqar
Adnan, Ahmad
Ng, Seik Weng
author_facet Akbar, Muhammad
Quereshi, Fahim Ashraf
Nasir, Waqar
Adnan, Ahmad
Ng, Seik Weng
author_sort Akbar, Muhammad
collection PubMed
description The –SCH(2)CH(2)CH(2)CH(2)S– portion of the title compound, C(12)H(14)N(2)S(2), adopts an extended zigzag conformation. The angles at the tetra­hedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S—C—C and C—C—C respectively] from the idealized tetra­hedral angle. The mol­ecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, there is a π–π stacking inter­action between inversion-related pyrimidine rings with mean inter­planar spacing of 3.494 (2) Å.
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spelling pubmed-30092222010-12-30 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane Akbar, Muhammad Quereshi, Fahim Ashraf Nasir, Waqar Adnan, Ahmad Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The –SCH(2)CH(2)CH(2)CH(2)S– portion of the title compound, C(12)H(14)N(2)S(2), adopts an extended zigzag conformation. The angles at the tetra­hedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S—C—C and C—C—C respectively] from the idealized tetra­hedral angle. The mol­ecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, there is a π–π stacking inter­action between inversion-related pyrimidine rings with mean inter­planar spacing of 3.494 (2) Å. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009222/ /pubmed/21589034 http://dx.doi.org/10.1107/S1600536810041103 Text en © Akbar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akbar, Muhammad
Quereshi, Fahim Ashraf
Nasir, Waqar
Adnan, Ahmad
Ng, Seik Weng
1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title_full 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title_fullStr 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title_full_unstemmed 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title_short 1,4-Bis(pyrimidin-2-yl­sulfanyl)­butane
title_sort 1,4-bis(pyrimidin-2-yl­sulfanyl)­butane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009222/
https://www.ncbi.nlm.nih.gov/pubmed/21589034
http://dx.doi.org/10.1107/S1600536810041103
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AT adnanahmad 14bispyrimidin2ylsulfanylbutane
AT ngseikweng 14bispyrimidin2ylsulfanylbutane

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