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Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]thulium(III)} monohydrate
In the title dinuclear complex, [Tm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Tm(III) atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal–...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009223/ https://www.ncbi.nlm.nih.gov/pubmed/21588910 http://dx.doi.org/10.1107/S1600536810043898 |
| _version_ | 1782194636256706560 |
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| author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the title dinuclear complex, [Tm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Tm(III) atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal–prismatic geometry. While four of the HPAA ligands coordinate to just one Tm atom, the remaining two HPAA ligands bridge the two Tm atoms. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional network. |
| format | Text |
| id | pubmed-3009223 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30092232010-12-30 Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]thulium(III)} monohydrate Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Tm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Tm(III) atoms are coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine ligand in a distorted tricapped trigonal–prismatic geometry. While four of the HPAA ligands coordinate to just one Tm atom, the remaining two HPAA ligands bridge the two Tm atoms. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009223/ /pubmed/21588910 http://dx.doi.org/10.1107/S1600536810043898 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]thulium(III)} monohydrate |
| title | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]thulium(III)} monohydrate |
| title_full | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]thulium(III)} monohydrate |
| title_fullStr | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]thulium(III)} monohydrate |
| title_full_unstemmed | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]thulium(III)} monohydrate |
| title_short | Bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]thulium(III)} monohydrate |
| title_sort | bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o,o′:o;κ(3)
o:o,o′-bis{aqua(4,4′-bipyridine-κn)bis[2-(4-hydroxyphenyl)acetato-κ(2)
o,o′]thulium(iii)} monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009223/ https://www.ncbi.nlm.nih.gov/pubmed/21588910 http://dx.doi.org/10.1107/S1600536810043898 |
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