Bis(1H-pyrazole-κN (2))bis­(2,4,6-tri­isopropyl­benzoato-κO)cobalt(II)

The title compound, [Co(C(16)H(23)O(2))(2)(C(3)H(4)N(2))(2)] or (C(3)H(4)N(2))(2)Co(O(2)CC(6)H(2) (i)Pr(3)-2,4,6), is a rare example of a tetra­coordinate cobalt(II) carboxyl­ate stabilized by ancillary N-heterocyclic ligands. The Co(II) ion resides on a crystallographic twofold axis so that the asy...

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Detalles Bibliográficos
Autores principales: Hrib, Cristian G., Blaurock, Steffen, Edelmann, Frank T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009229/
https://www.ncbi.nlm.nih.gov/pubmed/21588824
http://dx.doi.org/10.1107/S1600536810039553
Descripción
Sumario:The title compound, [Co(C(16)H(23)O(2))(2)(C(3)H(4)N(2))(2)] or (C(3)H(4)N(2))(2)Co(O(2)CC(6)H(2) (i)Pr(3)-2,4,6), is a rare example of a tetra­coordinate cobalt(II) carboxyl­ate stabilized by ancillary N-heterocyclic ligands. The Co(II) ion resides on a crystallographic twofold axis so that the asymmetric unit comprises one half-mol­ecule. Due to the steric bulk of the 2,4,6-triisopropyl­phenyl substituents, the carboxyl­ate ligands are both coordinated in a monodentate fashion despite the low coordination number. The coordination geometry around the central Co(II) ion is distorted tetra­hedral with angles at Co ranging from 92.27 (18)° to 121.08 (14)°.

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