3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one

In the title compound, C(29)H(23)NO(2), the pyrrolidine ring adopts a twisted conformation about one of the C—N bonds. The acenaphthone ring (r.m.s. deviation = 0.025 Å) lies almost perpendicular to the pyrrolidine ring [dihedral angle = 88.08 (8)°]. The dihedral angle between the phenyl rings is 88...

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Detalles Bibliográficos
Autores principales: Augustine, T., Vithiya, Scholastica Mary, Ignacimuthu, S., Ramkumar, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009230/
https://www.ncbi.nlm.nih.gov/pubmed/21589163
http://dx.doi.org/10.1107/S160053681004376X
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author Augustine, T.
Vithiya, Scholastica Mary
Ignacimuthu, S.
Ramkumar, V.
author_facet Augustine, T.
Vithiya, Scholastica Mary
Ignacimuthu, S.
Ramkumar, V.
author_sort Augustine, T.
collection PubMed
description In the title compound, C(29)H(23)NO(2), the pyrrolidine ring adopts a twisted conformation about one of the C—N bonds. The acenaphthone ring (r.m.s. deviation = 0.025 Å) lies almost perpendicular to the pyrrolidine ring [dihedral angle = 88.08 (8)°]. The dihedral angle between the phenyl rings is 88.12 (11)°. In the crystal structure, weak C—H⋯π inter­actions connect the mol­ecules.
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spelling pubmed-30092302010-12-30 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one Augustine, T. Vithiya, Scholastica Mary Ignacimuthu, S. Ramkumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(23)NO(2), the pyrrolidine ring adopts a twisted conformation about one of the C—N bonds. The acenaphthone ring (r.m.s. deviation = 0.025 Å) lies almost perpendicular to the pyrrolidine ring [dihedral angle = 88.08 (8)°]. The dihedral angle between the phenyl rings is 88.12 (11)°. In the crystal structure, weak C—H⋯π inter­actions connect the mol­ecules. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009230/ /pubmed/21589163 http://dx.doi.org/10.1107/S160053681004376X Text en © Augustine et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Augustine, T.
Vithiya, Scholastica Mary
Ignacimuthu, S.
Ramkumar, V.
3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title_full 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title_fullStr 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title_full_unstemmed 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title_short 3′-Benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2H),2′-pyrrolidin]-2-one
title_sort 3′-benzoyl-1′-methyl-4′-phenyl­spiro[acenaphthyl­ene-1(2h),2′-pyrrolidin]-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009230/
https://www.ncbi.nlm.nih.gov/pubmed/21589163
http://dx.doi.org/10.1107/S160053681004376X
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