Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate

In the title compound, (C(24)H(20)As)(2)[Co(2)(C(6)H(6)NO(6))(2)(OH)(2)]·8H(2)O, the Co(III) atom in the binuclear centrosymmetric anion is octa­hedrally surrounded by one N atom and three O atoms of the tetra­dentate nitrilo­triacetate ligand and two μ-hydroxide ligands. The crystal packing is cont...

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Detalles Bibliográficos
Autores principales: Visser, Hendrik G., Clegg, Jack K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009231/
https://www.ncbi.nlm.nih.gov/pubmed/21588834
http://dx.doi.org/10.1107/S160053681003895X
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author Visser, Hendrik G.
Clegg, Jack K.
author_facet Visser, Hendrik G.
Clegg, Jack K.
author_sort Visser, Hendrik G.
collection PubMed
description In the title compound, (C(24)H(20)As)(2)[Co(2)(C(6)H(6)NO(6))(2)(OH)(2)]·8H(2)O, the Co(III) atom in the binuclear centrosymmetric anion is octa­hedrally surrounded by one N atom and three O atoms of the tetra­dentate nitrilo­triacetate ligand and two μ-hydroxide ligands. The crystal packing is controlled by C—H⋯O and O—H⋯O hydrogen-bonding inter­actions. The crystal employed in this study proved to be a two-component twin around (0[Image: see text]1).
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spelling pubmed-30092312010-12-30 Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate Visser, Hendrik G. Clegg, Jack K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(24)H(20)As)(2)[Co(2)(C(6)H(6)NO(6))(2)(OH)(2)]·8H(2)O, the Co(III) atom in the binuclear centrosymmetric anion is octa­hedrally surrounded by one N atom and three O atoms of the tetra­dentate nitrilo­triacetate ligand and two μ-hydroxide ligands. The crystal packing is controlled by C—H⋯O and O—H⋯O hydrogen-bonding inter­actions. The crystal employed in this study proved to be a two-component twin around (0[Image: see text]1). International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009231/ /pubmed/21588834 http://dx.doi.org/10.1107/S160053681003895X Text en © Visser and Clegg 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Visser, Hendrik G.
Clegg, Jack K.
Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title_full Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title_fullStr Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title_full_unstemmed Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title_short Bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(III)] octa­hydrate
title_sort bis(tetra­phenyl­arsonium) di-μ-hy­droxido-bis­[(nitrilo­triacetato)­cobalt(iii)] octa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009231/
https://www.ncbi.nlm.nih.gov/pubmed/21588834
http://dx.doi.org/10.1107/S160053681003895X
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