Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate

The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232/
https://www.ncbi.nlm.nih.gov/pubmed/21588813
http://dx.doi.org/10.1107/S1600536810039450
Descripción
Sumario:The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol­ecule could reasonably be located there.

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