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Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate

The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232/
https://www.ncbi.nlm.nih.gov/pubmed/21588813
http://dx.doi.org/10.1107/S1600536810039450
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol­ecule could reasonably be located there.
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spelling pubmed-30092322010-12-30 Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol­ecule could reasonably be located there. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009232/ /pubmed/21588813 http://dx.doi.org/10.1107/S1600536810039450 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title_full Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title_fullStr Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title_full_unstemmed Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title_short Tribenzylbis(triphenyl­arsine oxide-κO)tin(IV) tetra­phenyl­borate
title_sort tribenzylbis(triphenyl­arsine oxide-κo)tin(iv) tetra­phenyl­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232/
https://www.ncbi.nlm.nih.gov/pubmed/21588813
http://dx.doi.org/10.1107/S1600536810039450
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