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Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate
The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232/ https://www.ncbi.nlm.nih.gov/pubmed/21588813 http://dx.doi.org/10.1107/S1600536810039450 |
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author | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
author_facet | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
author_sort | Keng, Thy Chun |
collection | PubMed |
description | The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent molecule could reasonably be located there. |
format | Text |
id | pubmed-3009232 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30092322010-12-30 Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C–Sn–C angles 360.0 (3)° and O–Sn–O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent molecule could reasonably be located there. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009232/ /pubmed/21588813 http://dx.doi.org/10.1107/S1600536810039450 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title | Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title_full | Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title_fullStr | Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title_full_unstemmed | Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title_short | Tribenzylbis(triphenylarsine oxide-κO)tin(IV) tetraphenylborate |
title_sort | tribenzylbis(triphenylarsine oxide-κo)tin(iv) tetraphenylborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009232/ https://www.ncbi.nlm.nih.gov/pubmed/21588813 http://dx.doi.org/10.1107/S1600536810039450 |
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