N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline

In the title compound, C(18)H(17)ClN(2)O, the quinoline ring system is essentially planar; the r.m.s. deviation for the non-H atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH(2)– group. The meth­oxy-substituted benzene ring forms a dihedral...

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Autores principales: Boulcina, Raouf, Benhamoud, Nassima, Bouacida, Sofiane, Roisnel, Thierry, Debache, Abdelmadjid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009236/
https://www.ncbi.nlm.nih.gov/pubmed/21589041
http://dx.doi.org/10.1107/S1600536810041061
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author Boulcina, Raouf
Benhamoud, Nassima
Bouacida, Sofiane
Roisnel, Thierry
Debache, Abdelmadjid
author_facet Boulcina, Raouf
Benhamoud, Nassima
Bouacida, Sofiane
Roisnel, Thierry
Debache, Abdelmadjid
author_sort Boulcina, Raouf
collection PubMed
description In the title compound, C(18)H(17)ClN(2)O, the quinoline ring system is essentially planar; the r.m.s. deviation for the non-H atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH(2)– group. The meth­oxy-substituted benzene ring forms a dihedral angle of 70.22 (4)° with this ring system. The crystal structure can be described as zigzag layers in which the quinoline ring systems are parallel to (011) and molecules are connected via inter­molecular N—H⋯N hydrogen bonds, forming chains along [100]. The crystal studied was an inversion twin with a 0.86 (5):0.14 (5) domain ratio.
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spelling pubmed-30092362010-12-30 N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline Boulcina, Raouf Benhamoud, Nassima Bouacida, Sofiane Roisnel, Thierry Debache, Abdelmadjid Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)ClN(2)O, the quinoline ring system is essentially planar; the r.m.s. deviation for the non-H atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH(2)– group. The meth­oxy-substituted benzene ring forms a dihedral angle of 70.22 (4)° with this ring system. The crystal structure can be described as zigzag layers in which the quinoline ring systems are parallel to (011) and molecules are connected via inter­molecular N—H⋯N hydrogen bonds, forming chains along [100]. The crystal studied was an inversion twin with a 0.86 (5):0.14 (5) domain ratio. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009236/ /pubmed/21589041 http://dx.doi.org/10.1107/S1600536810041061 Text en © Boulcina et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boulcina, Raouf
Benhamoud, Nassima
Bouacida, Sofiane
Roisnel, Thierry
Debache, Abdelmadjid
N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title_full N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title_fullStr N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title_full_unstemmed N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title_short N-[(2-Chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
title_sort n-[(2-chloro-8-methyl­quinolin-3-yl)meth­yl]-4-meth­oxy­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009236/
https://www.ncbi.nlm.nih.gov/pubmed/21589041
http://dx.doi.org/10.1107/S1600536810041061
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