2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole

The title compound, C(16)H(18)N(4)S(2), was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis­(bromo­meth­yl)-2,5-dimethyl­benzene. The mol­ecule is located on a crystallographic centre of inversion and therefore adopts a trans c...

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Detalles Bibliográficos
Autores principales: Applewhite, Malcolm J., Potts, Storm V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009242/
https://www.ncbi.nlm.nih.gov/pubmed/21588954
http://dx.doi.org/10.1107/S1600536810039607
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author Applewhite, Malcolm J.
Potts, Storm V.
author_facet Applewhite, Malcolm J.
Potts, Storm V.
author_sort Applewhite, Malcolm J.
collection PubMed
description The title compound, C(16)H(18)N(4)S(2), was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis­(bromo­meth­yl)-2,5-dimethyl­benzene. The mol­ecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An inter­molecular N—H⋯N hydrogen bond forms layers of mol­ecules parallel to ([Image: see text]03). The dihedral angle between the central and terminal rings is 174.8 (2)°.
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spelling pubmed-30092422010-12-30 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole Applewhite, Malcolm J. Potts, Storm V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(18)N(4)S(2), was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis­(bromo­meth­yl)-2,5-dimethyl­benzene. The mol­ecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An inter­molecular N—H⋯N hydrogen bond forms layers of mol­ecules parallel to ([Image: see text]03). The dihedral angle between the central and terminal rings is 174.8 (2)°. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009242/ /pubmed/21588954 http://dx.doi.org/10.1107/S1600536810039607 Text en © Applewhite and Potts 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Applewhite, Malcolm J.
Potts, Storm V.
2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_full 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_fullStr 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_full_unstemmed 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_short 2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole
title_sort 2-({4-[(1h-imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009242/
https://www.ncbi.nlm.nih.gov/pubmed/21588954
http://dx.doi.org/10.1107/S1600536810039607
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