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Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II)
In each of the two molecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octahedron, arising from its coordination by one water molecule, two pyridine molecules, and one O-...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009243/ https://www.ncbi.nlm.nih.gov/pubmed/21588793 http://dx.doi.org/10.1107/S1600536810038493 |
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author | Tai, Xi-Shi |
author_facet | Tai, Xi-Shi |
author_sort | Tai, Xi-Shi |
collection | PubMed |
description | In each of the two molecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octahedron, arising from its coordination by one water molecule, two pyridine molecules, and one O-monodentate and one O,O′-bidentate deprotonated N-p-tolysulfonyl-l-leucine ligand. In the crystal, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming chains along the c axis. An intramolecular O—H⋯O hydrogen bond occurs in one of the molecules. |
format | Text |
id | pubmed-3009243 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30092432010-12-30 Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) Tai, Xi-Shi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In each of the two molecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octahedron, arising from its coordination by one water molecule, two pyridine molecules, and one O-monodentate and one O,O′-bidentate deprotonated N-p-tolysulfonyl-l-leucine ligand. In the crystal, molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming chains along the c axis. An intramolecular O—H⋯O hydrogen bond occurs in one of the molecules. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009243/ /pubmed/21588793 http://dx.doi.org/10.1107/S1600536810038493 Text en © Xi-Shii Tai 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tai, Xi-Shi Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title | Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title_full | Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title_fullStr | Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title_full_unstemmed | Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title_short | Aquadipyridinebis(N-p-tolysulfonyl-l-leucinato)nickel(II) |
title_sort | aquadipyridinebis(n-p-tolysulfonyl-l-leucinato)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009243/ https://www.ncbi.nlm.nih.gov/pubmed/21588793 http://dx.doi.org/10.1107/S1600536810038493 |
work_keys_str_mv | AT taixishi aquadipyridinebisnptolysulfonyllleucinatonickelii |