Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)

In each of the two mol­ecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octa­hedron, arising from its coordination by one water mol­ecule, two pyridine mol­ecules, and one O-...

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Detalles Bibliográficos
Autor principal: Tai, Xi-Shi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009243/
https://www.ncbi.nlm.nih.gov/pubmed/21588793
http://dx.doi.org/10.1107/S1600536810038493
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author Tai, Xi-Shi
author_facet Tai, Xi-Shi
author_sort Tai, Xi-Shi
collection PubMed
description In each of the two mol­ecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octa­hedron, arising from its coordination by one water mol­ecule, two pyridine mol­ecules, and one O-monodentate and one O,O′-bidentate deprotonated N-p-tolysulfonyl-l-leucine ligand. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming chains along the c axis. An intra­molecular O—H⋯O hydrogen bond occurs in one of the mol­ecules.
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spelling pubmed-30092432010-12-30 Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II) Tai, Xi-Shi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In each of the two mol­ecules in the asymmetric unit of the title compound, [Ni(C(13)H(18)NO(4)S)(2)(C(5)H(5)N)(2)(H(2)O)], the geometry of the Ni(2+) ion is an extremely distorted trans-NiN(2)O(4) octa­hedron, arising from its coordination by one water mol­ecule, two pyridine mol­ecules, and one O-monodentate and one O,O′-bidentate deprotonated N-p-tolysulfonyl-l-leucine ligand. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming chains along the c axis. An intra­molecular O—H⋯O hydrogen bond occurs in one of the mol­ecules. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009243/ /pubmed/21588793 http://dx.doi.org/10.1107/S1600536810038493 Text en © Xi-Shii Tai 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tai, Xi-Shi
Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title_full Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title_fullStr Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title_full_unstemmed Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title_short Aqua­dipyridine­bis­(N-p-tolysulfonyl-l-leucinato)nickel(II)
title_sort aqua­dipyridine­bis­(n-p-tolysulfonyl-l-leucinato)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009243/
https://www.ncbi.nlm.nih.gov/pubmed/21588793
http://dx.doi.org/10.1107/S1600536810038493
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