(9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate

In the title compound, C(26)H(28)INO(4)·H(2)O, benzene rings are inclined at a dihedral angle of 69.9 (1)°. The N-containing ring exhibits a chair conformation, while the other rings approximate to envelope conformations. In the crystal, the uncoordinated water mol­ecule forms inter­molecular O—H⋯O...

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Detalles Bibliográficos
Autores principales: Zheng, Xing-Liang, Jiang, Ning-Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009244/
https://www.ncbi.nlm.nih.gov/pubmed/21589007
http://dx.doi.org/10.1107/S1600536810040286
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author Zheng, Xing-Liang
Jiang, Ning-Fei
author_facet Zheng, Xing-Liang
Jiang, Ning-Fei
author_sort Zheng, Xing-Liang
collection PubMed
description In the title compound, C(26)H(28)INO(4)·H(2)O, benzene rings are inclined at a dihedral angle of 69.9 (1)°. The N-containing ring exhibits a chair conformation, while the other rings approximate to envelope conformations. In the crystal, the uncoordinated water mol­ecule forms inter­molecular O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-30092442010-12-30 (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate Zheng, Xing-Liang Jiang, Ning-Fei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(28)INO(4)·H(2)O, benzene rings are inclined at a dihedral angle of 69.9 (1)°. The N-containing ring exhibits a chair conformation, while the other rings approximate to envelope conformations. In the crystal, the uncoordinated water mol­ecule forms inter­molecular O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009244/ /pubmed/21589007 http://dx.doi.org/10.1107/S1600536810040286 Text en © Zheng and Jiang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Xing-Liang
Jiang, Ning-Fei
(9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_full (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_fullStr (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_full_unstemmed (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_short (9S,13R,14S)-7,8-Didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
title_sort (9s,13r,14s)-7,8-didehydro-4-(4-iodo­benz­yloxy)-3,7-dimeth­oxy-17-methyl­morphinan-6-one monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009244/
https://www.ncbi.nlm.nih.gov/pubmed/21589007
http://dx.doi.org/10.1107/S1600536810040286
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