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Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)neodymium(III)
In the mononuclear title complex, [Nd(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Nd(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and t...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009246/ https://www.ncbi.nlm.nih.gov/pubmed/21588886 http://dx.doi.org/10.1107/S1600536810042583 |
| _version_ | 1782194641778507776 |
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| author | Zheng, Junjia Jin, Hongxiao Ge, Hongliang |
| author_facet | Zheng, Junjia Jin, Hongxiao Ge, Hongliang |
| author_sort | Zheng, Junjia |
| collection | PubMed |
| description | In the mononuclear title complex, [Nd(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Nd(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and two O atoms from a nitrate anion. π–π stacking interactions between the phen and DHB ligands of adjacent complexes [centroid–centroid distances = 3.520 (6) and 3.798 (6) Å] stabilize the crystal structure. Intramolecular O—H⋯O hydrogen bonds are observed in the DHB ligands. |
| format | Text |
| id | pubmed-3009246 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30092462010-12-30 Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)neodymium(III) Zheng, Junjia Jin, Hongxiao Ge, Hongliang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Nd(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Nd(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and two O atoms from a nitrate anion. π–π stacking interactions between the phen and DHB ligands of adjacent complexes [centroid–centroid distances = 3.520 (6) and 3.798 (6) Å] stabilize the crystal structure. Intramolecular O—H⋯O hydrogen bonds are observed in the DHB ligands. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009246/ /pubmed/21588886 http://dx.doi.org/10.1107/S1600536810042583 Text en © Zheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zheng, Junjia Jin, Hongxiao Ge, Hongliang Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)neodymium(III) |
| title | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
| title_full | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
| title_fullStr | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
| title_full_unstemmed | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
| title_short | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)neodymium(III) |
| title_sort | bis(2,6-dihydroxybenzoato-κ(2)
o
(1),o
(1′))(nitrato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)neodymium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009246/ https://www.ncbi.nlm.nih.gov/pubmed/21588886 http://dx.doi.org/10.1107/S1600536810042583 |
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