catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]

In the title compound, {[Fe(C(2)N(10))(H(2)O)(4)]·2H(2)O}(n), the coordin­ation geometry around the Fe(II) atom, which lies on a center of inversion, is distorted octa­hedral, with bonds to four O atoms and two N atoms. The azotetra­zolate ligand displays a bridging coordination mode, forming an inf...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiao, Bao-juan, Yan, Zhi-jun, Fan, Guang, Chen, San-ping, Gao, Sheng-li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009247/
https://www.ncbi.nlm.nih.gov/pubmed/21588815
http://dx.doi.org/10.1107/S1600536810039632
_version_ 1782194642065817600
author Jiao, Bao-juan
Yan, Zhi-jun
Fan, Guang
Chen, San-ping
Gao, Sheng-li
author_facet Jiao, Bao-juan
Yan, Zhi-jun
Fan, Guang
Chen, San-ping
Gao, Sheng-li
author_sort Jiao, Bao-juan
collection PubMed
description In the title compound, {[Fe(C(2)N(10))(H(2)O)(4)]·2H(2)O}(n), the coordin­ation geometry around the Fe(II) atom, which lies on a center of inversion, is distorted octa­hedral, with bonds to four O atoms and two N atoms. The azotetra­zolate ligand displays a bridging coordination mode, forming an infinite zigzag chain. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonding and offset face-to-face π–π stacking inter­actions [centroid–centroid distance = 3.4738 (13) Å] lead to a three-dimensional network.
format Text
id pubmed-3009247
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092472010-12-30 catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate] Jiao, Bao-juan Yan, Zhi-jun Fan, Guang Chen, San-ping Gao, Sheng-li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Fe(C(2)N(10))(H(2)O)(4)]·2H(2)O}(n), the coordin­ation geometry around the Fe(II) atom, which lies on a center of inversion, is distorted octa­hedral, with bonds to four O atoms and two N atoms. The azotetra­zolate ligand displays a bridging coordination mode, forming an infinite zigzag chain. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonding and offset face-to-face π–π stacking inter­actions [centroid–centroid distance = 3.4738 (13) Å] lead to a three-dimensional network. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009247/ /pubmed/21588815 http://dx.doi.org/10.1107/S1600536810039632 Text en © Jiao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiao, Bao-juan
Yan, Zhi-jun
Fan, Guang
Chen, San-ping
Gao, Sheng-li
catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title_full catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title_fullStr catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title_short catena-Poly[[[tetra­aqua­iron(II)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
title_sort catena-poly[[[tetra­aqua­iron(ii)]-μ-5,5′-diazenediylditetra­zolido] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009247/
https://www.ncbi.nlm.nih.gov/pubmed/21588815
http://dx.doi.org/10.1107/S1600536810039632
work_keys_str_mv AT jiaobaojuan catenapolytetraaquaironiim55diazenediylditetrazolidodihydrate
AT yanzhijun catenapolytetraaquaironiim55diazenediylditetrazolidodihydrate
AT fanguang catenapolytetraaquaironiim55diazenediylditetrazolidodihydrate
AT chensanping catenapolytetraaquaironiim55diazenediylditetrazolidodihydrate
AT gaoshengli catenapolytetraaquaironiim55diazenediylditetrazolidodihydrate

Ejemplares similares