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1,2,4,5-Tetrafluoro-3,6-diiodobenzene–2,3-bis(pyridin-2-yl)pyrazine (1/1)
The components of the title 1:1 co-crystal, C(14)H(10)N(4)·C(6)F(4)I(2), are connected via an N⋯I [2.959 (4) Å] halogen bond, in which the N atom is part of the relatively electron-rich pyrazine ring. The C(6)F(4)I(2) molecule is almost planar [r.m.s. deviation = 0.038 Å] but there are significant...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009248/ https://www.ncbi.nlm.nih.gov/pubmed/21589066 http://dx.doi.org/10.1107/S1600536810041668 |
Sumario: | The components of the title 1:1 co-crystal, C(14)H(10)N(4)·C(6)F(4)I(2), are connected via an N⋯I [2.959 (4) Å] halogen bond, in which the N atom is part of the relatively electron-rich pyrazine ring. The C(6)F(4)I(2) molecule is almost planar [r.m.s. deviation = 0.038 Å] but there are significant twists in the pyrazine derivative, as seen in the dihedral angles [31.3 (2) and 54.6 (2)°] formed between the pendant pyridyl rings and the central pyrazine ring. The bimolecular aggregates are sustained in the crystal by C—H⋯F and π–π interactions [ring centroid(pyridyl)–ring centroid(benzene) = 3.678 (3) Å]. |
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