1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)

The components of the title 1:1 co-crystal, C(14)H(10)N(4)·C(6)F(4)I(2), are connected via an N⋯I [2.959 (4) Å] halogen bond, in which the N atom is part of the relatively electron-rich pyrazine ring. The C(6)F(4)I(2) mol­ecule is almost planar [r.m.s. deviation = 0.038 Å] but there are significant...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Kaulgud, Trupta, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009248/
https://www.ncbi.nlm.nih.gov/pubmed/21589066
http://dx.doi.org/10.1107/S1600536810041668
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author Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The components of the title 1:1 co-crystal, C(14)H(10)N(4)·C(6)F(4)I(2), are connected via an N⋯I [2.959 (4) Å] halogen bond, in which the N atom is part of the relatively electron-rich pyrazine ring. The C(6)F(4)I(2) mol­ecule is almost planar [r.m.s. deviation = 0.038 Å] but there are significant twists in the pyrazine derivative, as seen in the dihedral angles [31.3 (2) and 54.6 (2)°] formed between the pendant pyridyl rings and the central pyrazine ring. The bimolecular aggregates are sustained in the crystal by C—H⋯F and π–π inter­actions [ring centroid(pyrid­yl)–ring centroid(benzene) = 3.678 (3) Å].
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spelling pubmed-30092482010-12-30 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The components of the title 1:1 co-crystal, C(14)H(10)N(4)·C(6)F(4)I(2), are connected via an N⋯I [2.959 (4) Å] halogen bond, in which the N atom is part of the relatively electron-rich pyrazine ring. The C(6)F(4)I(2) mol­ecule is almost planar [r.m.s. deviation = 0.038 Å] but there are significant twists in the pyrazine derivative, as seen in the dihedral angles [31.3 (2) and 54.6 (2)°] formed between the pendant pyridyl rings and the central pyrazine ring. The bimolecular aggregates are sustained in the crystal by C—H⋯F and π–π inter­actions [ring centroid(pyrid­yl)–ring centroid(benzene) = 3.678 (3) Å]. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009248/ /pubmed/21589066 http://dx.doi.org/10.1107/S1600536810041668 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title_full 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title_fullStr 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title_full_unstemmed 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title_short 1,2,4,5-Tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
title_sort 1,2,4,5-tetra­fluoro-3,6-diiodo­benzene–2,3-bis­(pyridin-2-yl)pyrazine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009248/
https://www.ncbi.nlm.nih.gov/pubmed/21589066
http://dx.doi.org/10.1107/S1600536810041668
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AT kaulgudtrupta 1245tetrafluoro36diiodobenzene23bispyridin2ylpyrazine11
AT tiekinkedwardrt 1245tetrafluoro36diiodobenzene23bispyridin2ylpyrazine11

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