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3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one

In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The mol­ecular conformation is stabilized by an almost symmetr...

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Autores principales: Asad, Mohammad, Oo, Chuan-Wei, Osman, Hasnah, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009251/
https://www.ncbi.nlm.nih.gov/pubmed/21589179
http://dx.doi.org/10.1107/S1600536810043837
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author Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Asad, Mohammad
collection PubMed
description In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The mol­ecular conformation is stabilized by an almost symmetric intra­molecular O⋯H⋯O hydrogen bond and a C—H⋯O inter­action, both of which form S(6) ring motifs. In the crystal structure, mol­ecules are linked into sheets lying parallel to (100) via inter­molecular C—H⋯O hydrogen bonds. The crystal packing is further consolidated by π–π stacking inter­actions [centroid-to-centroid separation = 3.6615 (6) Å].
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spelling pubmed-30092512010-12-30 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The mol­ecular conformation is stabilized by an almost symmetric intra­molecular O⋯H⋯O hydrogen bond and a C—H⋯O inter­action, both of which form S(6) ring motifs. In the crystal structure, mol­ecules are linked into sheets lying parallel to (100) via inter­molecular C—H⋯O hydrogen bonds. The crystal packing is further consolidated by π–π stacking inter­actions [centroid-to-centroid separation = 3.6615 (6) Å]. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009251/ /pubmed/21589179 http://dx.doi.org/10.1107/S1600536810043837 Text en © Asad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asad, Mohammad
Oo, Chuan-Wei
Osman, Hasnah
Quah, Ching Kheng
Fun, Hoong-Kun
3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title_full 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title_fullStr 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title_full_unstemmed 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title_short 3-[(E)-3-(2,4-Dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2H-chromen-2-one
title_sort 3-[(e)-3-(2,4-dichloro­phen­yl)prop-2-en­oyl]-4-hy­droxy-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009251/
https://www.ncbi.nlm.nih.gov/pubmed/21589179
http://dx.doi.org/10.1107/S1600536810043837
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