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3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one
In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The molecular conformation is stabilized by an almost symmetr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009251/ https://www.ncbi.nlm.nih.gov/pubmed/21589179 http://dx.doi.org/10.1107/S1600536810043837 |
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author | Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Asad, Mohammad |
collection | PubMed |
description | In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The molecular conformation is stabilized by an almost symmetric intramolecular O⋯H⋯O hydrogen bond and a C—H⋯O interaction, both of which form S(6) ring motifs. In the crystal structure, molecules are linked into sheets lying parallel to (100) via intermolecular C—H⋯O hydrogen bonds. The crystal packing is further consolidated by π–π stacking interactions [centroid-to-centroid separation = 3.6615 (6) Å]. |
format | Text |
id | pubmed-3009251 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30092512010-12-30 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(10)Cl(2)O(4), the chromen-2-one ring system is almost planar [maximum deviation = 0.028 (1) Å] and is inclined at an angle of 16.35 (4)° with respect to the benzene ring. The C=C bond has an E configuration. The molecular conformation is stabilized by an almost symmetric intramolecular O⋯H⋯O hydrogen bond and a C—H⋯O interaction, both of which form S(6) ring motifs. In the crystal structure, molecules are linked into sheets lying parallel to (100) via intermolecular C—H⋯O hydrogen bonds. The crystal packing is further consolidated by π–π stacking interactions [centroid-to-centroid separation = 3.6615 (6) Å]. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009251/ /pubmed/21589179 http://dx.doi.org/10.1107/S1600536810043837 Text en © Asad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asad, Mohammad Oo, Chuan-Wei Osman, Hasnah Quah, Ching Kheng Fun, Hoong-Kun 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title | 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title_full | 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title_fullStr | 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title_full_unstemmed | 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title_short | 3-[(E)-3-(2,4-Dichlorophenyl)prop-2-enoyl]-4-hydroxy-2H-chromen-2-one |
title_sort | 3-[(e)-3-(2,4-dichlorophenyl)prop-2-enoyl]-4-hydroxy-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009251/ https://www.ncbi.nlm.nih.gov/pubmed/21589179 http://dx.doi.org/10.1107/S1600536810043837 |
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