Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)

The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth­oxy-2-[(4-methyl­phen­yl)imino­meth­yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) i...

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Detalles Bibliográficos
Autor principal: Guo, Hang-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009253/
https://www.ncbi.nlm.nih.gov/pubmed/21588866
http://dx.doi.org/10.1107/S1600536810042194
Descripción
Sumario:The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth­oxy-2-[(4-methyl­phen­yl)imino­meth­yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu—O(deprotonated phenolate) bond and a weak Eu—O(meth­oxy) contact, the latter can be inter­preted as the apices of the bicapped square-anti­prismatic Eu(III) polyhedron. Intra­molecular N—H⋯O hydrogen bonds occur.

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