Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)

The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth­oxy-2-[(4-methyl­phen­yl)imino­meth­yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) i...

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Detalles Bibliográficos
Autor principal: Guo, Hang-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009253/
https://www.ncbi.nlm.nih.gov/pubmed/21588866
http://dx.doi.org/10.1107/S1600536810042194
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author Guo, Hang-Ming
author_facet Guo, Hang-Ming
author_sort Guo, Hang-Ming
collection PubMed
description The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth­oxy-2-[(4-methyl­phen­yl)imino­meth­yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu—O(deprotonated phenolate) bond and a weak Eu—O(meth­oxy) contact, the latter can be inter­preted as the apices of the bicapped square-anti­prismatic Eu(III) polyhedron. Intra­molecular N—H⋯O hydrogen bonds occur.
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spelling pubmed-30092532010-12-30 Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III) Guo, Hang-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth­oxy-2-[(4-methyl­phen­yl)imino­meth­yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu—O(deprotonated phenolate) bond and a weak Eu—O(meth­oxy) contact, the latter can be inter­preted as the apices of the bicapped square-anti­prismatic Eu(III) polyhedron. Intra­molecular N—H⋯O hydrogen bonds occur. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009253/ /pubmed/21588866 http://dx.doi.org/10.1107/S1600536810042194 Text en © Hang-Ming Guo 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Hang-Ming
Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title_full Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title_fullStr Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title_full_unstemmed Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title_short Bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(nitrato-κ(2) O,O′)europium(III)
title_sort bis{[6-meth­oxy-2-(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) o,o′}tris­(nitrato-κ(2) o,o′)europium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009253/
https://www.ncbi.nlm.nih.gov/pubmed/21588866
http://dx.doi.org/10.1107/S1600536810042194
work_keys_str_mv AT guohangming bis6methoxy24methylphenyliminiomethylphenolatek2ootrisnitratok2ooeuropiumiii

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