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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)]
In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octahedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand. Each oxalate ligand bridges two Cd(II) atoms, generating...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009255/ https://www.ncbi.nlm.nih.gov/pubmed/21588863 http://dx.doi.org/10.1107/S1600536810040341 |
| _version_ | 1782194643963740160 |
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| author | Lv, Yao-Kang Gan, Li-Hua Cao, Yong-Jie Gao, Biao-Feng Chen, Liu-Hua |
| author_facet | Lv, Yao-Kang Gan, Li-Hua Cao, Yong-Jie Gao, Biao-Feng Chen, Liu-Hua |
| author_sort | Lv, Yao-Kang |
| collection | PubMed |
| description | In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octahedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand. Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100]. The packing of the structure is consolidated by non-classical C—H⋯O hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-3009255 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30092552010-12-30 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] Lv, Yao-Kang Gan, Li-Hua Cao, Yong-Jie Gao, Biao-Feng Chen, Liu-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(2)O(4))(C(12)H(8)N(2))](n), the Cd(II) atom has a distorted octahedral coordination, defined by four O atoms from two symmetry-related oxalate ligands and by two N atoms from a bidentate 1,10-phenanthroline ligand. Each oxalate ligand bridges two Cd(II) atoms, generating a zigzag chain structure propagating along [100]. The packing of the structure is consolidated by non-classical C—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009255/ /pubmed/21588863 http://dx.doi.org/10.1107/S1600536810040341 Text en © Lv et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lv, Yao-Kang Gan, Li-Hua Cao, Yong-Jie Gao, Biao-Feng Chen, Liu-Hua catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] |
| title |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_fullStr |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_short |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] |
| title_sort | catena-poly[[(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii)]-μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009255/ https://www.ncbi.nlm.nih.gov/pubmed/21588863 http://dx.doi.org/10.1107/S1600536810040341 |
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