3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide

In the title compound, C(17)H(14)BrClN(4)O(2), the pyrazole ring is almost coplanar with the benzene ring [dihedral angle = 0.5 (2)°], whereas the pyrazole ring is close to perpendicular to the 3-chloro­pyridine ring [dihedral angle = 73.7 (2)°]. An intra­molecular C—H⋯O hydrogen bond occurs. The do...

Descripción completa

Detalles Bibliográficos
Autores principales: Yue, Hai, Dong, Wei-Li, Wang, Run-Ling, Cheng, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009256/
https://www.ncbi.nlm.nih.gov/pubmed/21589129
http://dx.doi.org/10.1107/S1600536810040158
_version_ 1782194644282507264
author Yue, Hai
Dong, Wei-Li
Wang, Run-Ling
Cheng, Xian-Chao
author_facet Yue, Hai
Dong, Wei-Li
Wang, Run-Ling
Cheng, Xian-Chao
author_sort Yue, Hai
collection PubMed
description In the title compound, C(17)H(14)BrClN(4)O(2), the pyrazole ring is almost coplanar with the benzene ring [dihedral angle = 0.5 (2)°], whereas the pyrazole ring is close to perpendicular to the 3-chloro­pyridine ring [dihedral angle = 73.7 (2)°]. An intra­molecular C—H⋯O hydrogen bond occurs. The dominant inter­action in the crystal packing is an N—H⋯N hydrogen bond, which generates a chain along the c axis. Weak inter­molecular C—H⋯O and C—H⋯N contacts are also observed
format Text
id pubmed-3009256
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30092562010-12-30 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide Yue, Hai Dong, Wei-Li Wang, Run-Ling Cheng, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(14)BrClN(4)O(2), the pyrazole ring is almost coplanar with the benzene ring [dihedral angle = 0.5 (2)°], whereas the pyrazole ring is close to perpendicular to the 3-chloro­pyridine ring [dihedral angle = 73.7 (2)°]. An intra­molecular C—H⋯O hydrogen bond occurs. The dominant inter­action in the crystal packing is an N—H⋯N hydrogen bond, which generates a chain along the c axis. Weak inter­molecular C—H⋯O and C—H⋯N contacts are also observed International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009256/ /pubmed/21589129 http://dx.doi.org/10.1107/S1600536810040158 Text en © Yue et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yue, Hai
Dong, Wei-Li
Wang, Run-Ling
Cheng, Xian-Chao
3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title_full 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title_fullStr 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title_full_unstemmed 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title_short 3-Bromo-1-(3-chloro­pyridin-2-yl)-N-(4-eth­oxy­phen­yl)-1H-pyrazole-5-carbox­amide
title_sort 3-bromo-1-(3-chloro­pyridin-2-yl)-n-(4-eth­oxy­phen­yl)-1h-pyrazole-5-carbox­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009256/
https://www.ncbi.nlm.nih.gov/pubmed/21589129
http://dx.doi.org/10.1107/S1600536810040158
work_keys_str_mv AT yuehai 3bromo13chloropyridin2yln4ethoxyphenyl1hpyrazole5carboxamide
AT dongweili 3bromo13chloropyridin2yln4ethoxyphenyl1hpyrazole5carboxamide
AT wangrunling 3bromo13chloropyridin2yln4ethoxyphenyl1hpyrazole5carboxamide
AT chengxianchao 3bromo13chloropyridin2yln4ethoxyphenyl1hpyrazole5carboxamide

Ejemplares similares