Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]

The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2−), parallel to the ab...

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Detalles Bibliográficos
Autores principales: Assani, Abderrazzak, Saadi, Mohamed, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009259/
https://www.ncbi.nlm.nih.gov/pubmed/21588799
http://dx.doi.org/10.1107/S1600536810038729
Descripción
Sumario:The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2−), parallel to the ab plane. The edge-sharing CdO(6) octa­hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl­ene­diammonium cation and the water mol­ecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N—H⋯O and O—H⋯O hydrogen bonds.

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