Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]

The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2−), parallel to the ab...

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Detalles Bibliográficos
Autores principales: Assani, Abderrazzak, Saadi, Mohamed, El Ammari, Lahcen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009259/
https://www.ncbi.nlm.nih.gov/pubmed/21588799
http://dx.doi.org/10.1107/S1600536810038729
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author Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_facet Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
author_sort Assani, Abderrazzak
collection PubMed
description The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2−), parallel to the ab plane. The edge-sharing CdO(6) octa­hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl­ene­diammonium cation and the water mol­ecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-30092592010-12-30 Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate] Assani, Abderrazzak Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2−), parallel to the ab plane. The edge-sharing CdO(6) octa­hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl­ene­diammonium cation and the water mol­ecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009259/ /pubmed/21588799 http://dx.doi.org/10.1107/S1600536810038729 Text en © Assani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assani, Abderrazzak
Saadi, Mohamed
El Ammari, Lahcen
Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title_full Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title_fullStr Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title_full_unstemmed Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title_short Poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
title_sort poly[ethyl­enediammonium [tris­[μ(3)-hydrogenphosphato(2−)]dicadmium] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009259/
https://www.ncbi.nlm.nih.gov/pubmed/21588799
http://dx.doi.org/10.1107/S1600536810038729
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AT saadimohamed polyethylenediammoniumtrism3hydrogenphosphato2dicadmiummonohydrate
AT elammarilahcen polyethylenediammoniumtrism3hydrogenphosphato2dicadmiummonohydrate

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