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2-(2,5-Dichloro­benzene­sulfonamido)-3-methyl­butanoic acid

The structure of the title compound, C(11)H(13)Cl(2)NO(4)S, shows one sulfonamide-O atom to lie almost in the plane of the benzene ring [C—C—S—O = −178.7 (2) °] and the other to one side [C—C—S—O = −49.4 (3)°]. Lying to the other side is the amine residue, which occupies a position almost perpendicu...

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Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, John, Peter, Iqbal, Haffsah, Sharif, Shahzad, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009271/
https://www.ncbi.nlm.nih.gov/pubmed/21589068
http://dx.doi.org/10.1107/S1600536810041620
Descripción
Sumario:The structure of the title compound, C(11)H(13)Cl(2)NO(4)S, shows one sulfonamide-O atom to lie almost in the plane of the benzene ring [C—C—S—O = −178.7 (2) °] and the other to one side [C—C—S—O = −49.4 (3)°]. Lying to the other side is the amine residue, which occupies a position almost perpendicular to the plane [C—S—N—C = 70.2 (2)°]; the carb­oxy­lic acid group is orientated to lie over the benzene ring. In the crystal, the appearance of an 11-membered {⋯OH⋯OCOH⋯OC(2)NH} synthon, which features the hy­droxy group forming both donor (to a carbonyl-O) and acceptor (from the amine-H) inter­actions, leads to the formation of a supra­molecular chain along the a axis. Chains are connected in the crystal structure by C—H⋯O contacts.