5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone

The mol­ecule of the title compound, C(8)H(8)BrN(3)OS, is close to being planar, with maximum deviations of −0.127 (3) and 0.135 (5) Å for the N atoms of the –NH– and NH(2)– groups, respectively. Intra­molecular N—H⋯N and O—H⋯N hydrogen bonds to the same acceptor N atom generate S(5) and S(6) ring m...

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Autores principales: Kargar, Hadi, Kia, Reza, Akkurt, Mehmet, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009273/
https://www.ncbi.nlm.nih.gov/pubmed/21589160
http://dx.doi.org/10.1107/S1600536810043357
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author Kargar, Hadi
Kia, Reza
Akkurt, Mehmet
Büyükgüngör, Orhan
author_facet Kargar, Hadi
Kia, Reza
Akkurt, Mehmet
Büyükgüngör, Orhan
author_sort Kargar, Hadi
collection PubMed
description The mol­ecule of the title compound, C(8)H(8)BrN(3)OS, is close to being planar, with maximum deviations of −0.127 (3) and 0.135 (5) Å for the N atoms of the –NH– and NH(2)– groups, respectively. Intra­molecular N—H⋯N and O—H⋯N hydrogen bonds to the same acceptor N atom generate S(5) and S(6) ring motifs. In the crystal structure, mol­ecules are connected into [010] chains by pairs of N—H⋯S hydrogen bonds with R (2) (2)(8) graph-set motifs. The crystal used for data collection was found to be an inversion twin.
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spelling pubmed-30092732010-12-30 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone Kargar, Hadi Kia, Reza Akkurt, Mehmet Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(8)H(8)BrN(3)OS, is close to being planar, with maximum deviations of −0.127 (3) and 0.135 (5) Å for the N atoms of the –NH– and NH(2)– groups, respectively. Intra­molecular N—H⋯N and O—H⋯N hydrogen bonds to the same acceptor N atom generate S(5) and S(6) ring motifs. In the crystal structure, mol­ecules are connected into [010] chains by pairs of N—H⋯S hydrogen bonds with R (2) (2)(8) graph-set motifs. The crystal used for data collection was found to be an inversion twin. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009273/ /pubmed/21589160 http://dx.doi.org/10.1107/S1600536810043357 Text en © Kargar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Akkurt, Mehmet
Büyükgüngör, Orhan
5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title_full 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title_fullStr 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title_full_unstemmed 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title_short 5-Bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
title_sort 5-bromo-2-hy­droxy­benzaldehyde thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009273/
https://www.ncbi.nlm.nih.gov/pubmed/21589160
http://dx.doi.org/10.1107/S1600536810043357
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AT buyukgungororhan 5bromo2hydroxybenzaldehydethiosemicarbazone

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