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catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO (1))neodymium(III)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] tetrahydrate]
In the title coordination polymer, {[Nd(C(5)H(2)N(3)O(6))(C(2)O(4))(H(2)O)(4)]·4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic an...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009275/ https://www.ncbi.nlm.nih.gov/pubmed/21588856 http://dx.doi.org/10.1107/S1600536810041139 |
| _version_ | 1782194648985370624 |
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| author | Han, Yin-Feng Ng, Seik Weng |
| author_facet | Han, Yin-Feng Ng, Seik Weng |
| author_sort | Han, Yin-Feng |
| collection | PubMed |
| description | In the title coordination polymer, {[Nd(C(5)H(2)N(3)O(6))(C(2)O(4))(H(2)O)(4)]·4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules. |
| format | Text |
| id | pubmed-3009275 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30092752010-12-30 catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO (1))neodymium(III)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] tetrahydrate] Han, Yin-Feng Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Nd(C(5)H(2)N(3)O(6))(C(2)O(4))(H(2)O)(4)]·4H(2)O}(n), the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O—H⋯O hydrogen bonds involving the coordinated and uncoordinated water molecules. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009275/ /pubmed/21588856 http://dx.doi.org/10.1107/S1600536810041139 Text en © Han and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Han, Yin-Feng Ng, Seik Weng catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO (1))neodymium(III)]-μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)] tetrahydrate] |
| title |
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO
(1))neodymium(III)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] tetrahydrate] |
| title_full |
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO
(1))neodymium(III)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] tetrahydrate] |
| title_fullStr |
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO
(1))neodymium(III)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] tetrahydrate] |
| title_full_unstemmed |
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO
(1))neodymium(III)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] tetrahydrate] |
| title_short |
catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-κO
(1))neodymium(III)]-μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)] tetrahydrate] |
| title_sort | catena-poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine n-oxide-κo
(1))neodymium(iii)]-μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)] tetrahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009275/ https://www.ncbi.nlm.nih.gov/pubmed/21588856 http://dx.doi.org/10.1107/S1600536810041139 |
| work_keys_str_mv | AT hanyinfeng catenapolytetraaqua35dinitro4oxidopyridinenoxideko1neodymiumiiimoxalatok4o1o2o1o2tetrahydrate AT ngseikweng catenapolytetraaqua35dinitro4oxidopyridinenoxideko1neodymiumiiimoxalatok4o1o2o1o2tetrahydrate |