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9-Phenyl-10H-acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (−), the cations are linked to each other by very weak C—H⋯π inter­actions, while the cations and anions are connected by N—H⋯O, C—H⋯O and S—O⋯π inter­actions. The acridine ring system and the phenyl ring are oriented at an an...

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Autores principales: Trzybiński, Damian, Zadykowicz, Beata, Krzymiński, Karol, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009277/
https://www.ncbi.nlm.nih.gov/pubmed/21589031
http://dx.doi.org/10.1107/S1600536810040900
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author Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (−), the cations are linked to each other by very weak C—H⋯π inter­actions, while the cations and anions are connected by N—H⋯O, C—H⋯O and S—O⋯π inter­actions. The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°. The trifluoro­methane­sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8).
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spelling pubmed-30092772010-12-30 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate Trzybiński, Damian Zadykowicz, Beata Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(19)H(14)N(+)·CF(3)SO(3) (−), the cations are linked to each other by very weak C—H⋯π inter­actions, while the cations and anions are connected by N—H⋯O, C—H⋯O and S—O⋯π inter­actions. The acridine ring system and the phenyl ring are oriented at an angle of 80.1 (1)° with respect to each other. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 35.6 (1)°. The trifluoro­methane­sulfonate anions are disordered over two positions; the site occupancy factors are 0.591 (8) and 0.409 (8). International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009277/ /pubmed/21589031 http://dx.doi.org/10.1107/S1600536810040900 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Zadykowicz, Beata
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title_full 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title_fullStr 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title_short 9-Phenyl-10H-acridinium trifluoro­methane­sulfonate
title_sort 9-phenyl-10h-acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009277/
https://www.ncbi.nlm.nih.gov/pubmed/21589031
http://dx.doi.org/10.1107/S1600536810040900
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